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[M(OOCC6H4PO3H)(H2O)] (M(II) = Mn, Co, Ni): layered metal phosphonates showing variable magnetic behavior

[M(OOCC6H4PO3H)(H2O)] (M(II) = Mn, Co, Ni): layered metal phosphonates showing variable magnetic behavior
[M(OOCC6H4PO3H)(H2O)] (M(II) = Mn, Co, Ni): layered metal phosphonates showing variable magnetic behavior
Three novel isomorphous transition metal phosphonate compounds with formula [M(OOCC6H4PO3H)(H2O)] [M(II) = Mn(1), Co(2), Ni(3)] were prepared through hydrothermal reaction of 2-carboxyphenylphosphonic acid and metal salts. Within the structure, the {M2O2} dimers made up of edge-sharing{MO6} octahedra are connected by carboxylate and/orphosphonate groups, leading to a 2-D layer. The phenyl groups fill in the inter-layer spaces. Magnetic measurements reveal that dominant antiferromagnetic interactions are observed in compounds 1 and 2, while for compound 3, the dominant ferromagnetic interaction leads to a spontaneous ferromagnetic long range ordering below T-c = 4.0 K.
1466-8033
1255-1260
Li, Jin-Tang
8ae6b885-4b66-410e-87ff-7f85f1783f74
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Cao, Deng-Ke
c4c0f05c-d36e-450e-b229-1be50bc4709a
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
Zheng, Li-Min
8f592e4c-4875-47ea-a7eb-e7ad5a0128f9
Li, Jin-Tang
8ae6b885-4b66-410e-87ff-7f85f1783f74
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Cao, Deng-Ke
c4c0f05c-d36e-450e-b229-1be50bc4709a
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
Zheng, Li-Min
8f592e4c-4875-47ea-a7eb-e7ad5a0128f9

Li, Jin-Tang, Keene, Tony D., Cao, Deng-Ke, Decurtins, Silvio and Zheng, Li-Min (2009) [M(OOCC6H4PO3H)(H2O)] (M(II) = Mn, Co, Ni): layered metal phosphonates showing variable magnetic behavior. CrystEngComm, 11 (7), 1255-1260. (doi:10.1039/b820935a).

Record type: Article

Abstract

Three novel isomorphous transition metal phosphonate compounds with formula [M(OOCC6H4PO3H)(H2O)] [M(II) = Mn(1), Co(2), Ni(3)] were prepared through hydrothermal reaction of 2-carboxyphenylphosphonic acid and metal salts. Within the structure, the {M2O2} dimers made up of edge-sharing{MO6} octahedra are connected by carboxylate and/orphosphonate groups, leading to a 2-D layer. The phenyl groups fill in the inter-layer spaces. Magnetic measurements reveal that dominant antiferromagnetic interactions are observed in compounds 1 and 2, while for compound 3, the dominant ferromagnetic interaction leads to a spontaneous ferromagnetic long range ordering below T-c = 4.0 K.

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More information

Published date: 2009
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 351389
URI: http://eprints.soton.ac.uk/id/eprint/351389
ISSN: 1466-8033
PURE UUID: 6182fe7d-836c-45fb-a42c-6c9f743b225e
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327

Catalogue record

Date deposited: 22 Apr 2013 10:49
Last modified: 14 Mar 2024 13:39

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Contributors

Author: Jin-Tang Li
Author: Tony D. Keene ORCID iD
Author: Deng-Ke Cao
Author: Silvio Decurtins
Author: Li-Min Zheng

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