trans-bis(2-aminoanilinium-kappa N-2)bis(oxalato-kappa O-2,O')copper(II)
trans-bis(2-aminoanilinium-kappa N-2)bis(oxalato-kappa O-2,O')copper(II)
The title compound, [Cu(C2O4)(2)(C6H9N2)(2)], crystallizes in the space group P2(1)/c, with the Cu atom located at a centre of symmetry. It is a neutral coordination complex in which the metal exhibits a tetragonally elongated octahedral trans-CuO4N2 coordination environment. Extensive intermolecular hydrogen bonding between the oxalate anions and the ammonium cations determines the molecular packing in the crystal.
m1131-m1133
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
December 2003
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Keene, Tony D., Hursthouse, Michael B. and Price, Daniel J.
(2003)
trans-bis(2-aminoanilinium-kappa N-2)bis(oxalato-kappa O-2,O')copper(II).
Acta Crystallographica Section E: Crystallographic Communications, 59 (12), .
(doi:10.1107/S1600536803025613).
Abstract
The title compound, [Cu(C2O4)(2)(C6H9N2)(2)], crystallizes in the space group P2(1)/c, with the Cu atom located at a centre of symmetry. It is a neutral coordination complex in which the metal exhibits a tetragonally elongated octahedral trans-CuO4N2 coordination environment. Extensive intermolecular hydrogen bonding between the oxalate anions and the ammonium cations determines the molecular packing in the crystal.
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Published date: December 2003
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
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Local EPrints ID: 351399
URI: http://eprints.soton.ac.uk/id/eprint/351399
PURE UUID: 58c9b379-e221-456d-bb2b-dc19269dd7f9
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Date deposited: 22 Apr 2013 14:31
Last modified: 14 Mar 2024 13:39
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Author:
Tony D. Keene
Author:
Daniel J. Price
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