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Ready synthetic access to enantiopure allylic ?(F)-branched fluoroalkenes

Ready synthetic access to enantiopure allylic ?(F)-branched fluoroalkenes
Ready synthetic access to enantiopure allylic ?(F)-branched fluoroalkenes
Convenient access to homochiral fluoroalkenes is described via a Julia–Kocienski olefination reaction. The required homochiral fluorosulfone is synthesized by a Mitsunobu reaction from readily available enantiopure secondary alcohols
1523-7060
2450-2453
Larnaud, Florent
b5b03dcb-6c7e-4232-8a38-4bf904805a18
Malassis, Julien
4473f5cb-70c4-43f8-8389-9efe0a72e914
Pfund, Emmanuel
ecfd6437-1953-4e22-9638-42d0d9f11bed
Linclau, Bruno
19b9cacd-b8e8-4c65-af36-6352cade84ba
Lequeux, Thierry
52eca0ba-760f-457b-9d61-52df125721b2
Larnaud, Florent
b5b03dcb-6c7e-4232-8a38-4bf904805a18
Malassis, Julien
4473f5cb-70c4-43f8-8389-9efe0a72e914
Pfund, Emmanuel
ecfd6437-1953-4e22-9638-42d0d9f11bed
Linclau, Bruno
19b9cacd-b8e8-4c65-af36-6352cade84ba
Lequeux, Thierry
52eca0ba-760f-457b-9d61-52df125721b2

Larnaud, Florent, Malassis, Julien, Pfund, Emmanuel, Linclau, Bruno and Lequeux, Thierry (2013) Ready synthetic access to enantiopure allylic ?(F)-branched fluoroalkenes. Organic Letters, 15 (10), 2450-2453. (doi:10.1021/ol400917j).

Record type: Article

Abstract

Convenient access to homochiral fluoroalkenes is described via a Julia–Kocienski olefination reaction. The required homochiral fluorosulfone is synthesized by a Mitsunobu reaction from readily available enantiopure secondary alcohols

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More information

Published date: May 2013

Identifiers

Local EPrints ID: 353409
URI: http://eprints.soton.ac.uk/id/eprint/353409
DOI: doi:10.1021/ol400917j
ISSN: 1523-7060
PURE UUID: b71b1d3f-baa4-45f6-a4c0-bbc9c62c0372
ORCID for Bruno Linclau: ORCID iD orcid.org/0000-0001-8762-0170

Catalogue record

Date deposited: 06 Jun 2013 07:29
Last modified: 15 Mar 2024 03:05

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Contributors

Author: Florent Larnaud
Author: Julien Malassis
Author: Emmanuel Pfund
Author: Bruno Linclau ORCID iD
Author: Thierry Lequeux

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