Site-selective synthesis of Janus-type metal-organic framework composites
Site-selective synthesis of Janus-type metal-organic framework composites
Herein, bipolar electrochemistry is applied in a straightforward way to the site-selective in situ synthesis of metal–organic framework (MOF) structures, which have attracted tremendous interest in recent years because of their significant application potential, ranging from sensing to gas storage and catalysis. The novelty of the presented work is that the deposit can be intentionally confined to a defined area of a substrate without using masks or templates. The intrinsic site-selectivity of bipolar electrochemistry makes it a method of choice to generate, in a highly controlled way, hybrid particles that may have different functionalities combined on the same particle. The wireless nature of electrodeposition allows the potential for mass production of such Janus-type objects.
composites, electrochemistry, electrocrystallization, janus particles, metal-organic frameworks
4001-4005
Yadnum, Sudarat
234f3d24-295c-4954-b6dd-594423d9a272
Roche, Jérome
42b07bfc-5921-442b-be32-ded6285ab19b
Lebraud, Eric
e408fb99-a507-4f9f-ad38-664e0f83fa26
Négrier, Philippe
b7e32da0-8f80-442d-8a6a-3ea6d006f339
Garrigue, Patrick
5b8400a0-7045-4ca1-828a-6e52539927a9
Bradshaw, Darren
7677b11e-1961-447e-b9ba-4847a74bd4dd
Warakulwit, Chompunuch
96b04751-535a-4bb4-ba60-50fcf5e3917a
Limtrakul, Jumras
9c2fa444-5d68-4675-9fa4-248162eb1afd
Kuhn, Alexander
73f46b8f-b350-4c8a-8ce5-590930408086
7 April 2014
Yadnum, Sudarat
234f3d24-295c-4954-b6dd-594423d9a272
Roche, Jérome
42b07bfc-5921-442b-be32-ded6285ab19b
Lebraud, Eric
e408fb99-a507-4f9f-ad38-664e0f83fa26
Négrier, Philippe
b7e32da0-8f80-442d-8a6a-3ea6d006f339
Garrigue, Patrick
5b8400a0-7045-4ca1-828a-6e52539927a9
Bradshaw, Darren
7677b11e-1961-447e-b9ba-4847a74bd4dd
Warakulwit, Chompunuch
96b04751-535a-4bb4-ba60-50fcf5e3917a
Limtrakul, Jumras
9c2fa444-5d68-4675-9fa4-248162eb1afd
Kuhn, Alexander
73f46b8f-b350-4c8a-8ce5-590930408086
Yadnum, Sudarat, Roche, Jérome, Lebraud, Eric, Négrier, Philippe, Garrigue, Patrick, Bradshaw, Darren, Warakulwit, Chompunuch, Limtrakul, Jumras and Kuhn, Alexander
(2014)
Site-selective synthesis of Janus-type metal-organic framework composites.
Angewandte Chemie International Edition, 53 (15), .
(doi:10.1002/anie.201400581).
Abstract
Herein, bipolar electrochemistry is applied in a straightforward way to the site-selective in situ synthesis of metal–organic framework (MOF) structures, which have attracted tremendous interest in recent years because of their significant application potential, ranging from sensing to gas storage and catalysis. The novelty of the presented work is that the deposit can be intentionally confined to a defined area of a substrate without using masks or templates. The intrinsic site-selectivity of bipolar electrochemistry makes it a method of choice to generate, in a highly controlled way, hybrid particles that may have different functionalities combined on the same particle. The wireless nature of electrodeposition allows the potential for mass production of such Janus-type objects.
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e-pub ahead of print date: 6 March 2014
Published date: 7 April 2014
Keywords:
composites, electrochemistry, electrocrystallization, janus particles, metal-organic frameworks
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 363387
URI: http://eprints.soton.ac.uk/id/eprint/363387
ISSN: 1433-7851
PURE UUID: 29396b7e-f369-4210-8e84-2c1fa9be2225
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Date deposited: 25 Mar 2014 11:17
Last modified: 15 Mar 2024 03:40
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Contributors
Author:
Sudarat Yadnum
Author:
Jérome Roche
Author:
Eric Lebraud
Author:
Philippe Négrier
Author:
Patrick Garrigue
Author:
Chompunuch Warakulwit
Author:
Jumras Limtrakul
Author:
Alexander Kuhn
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