A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks
A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks
The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn-12(III)] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.
10690
Frost, J. M.
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Sanz, S.
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Rajeshkumar, T.
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Pitak, M. B.
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Coles, S. J.
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Rajaraman, G.
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Wernsdorfer, W.
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Schnack, J.
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Lusby, P. J.
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Brechin, E. K.
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22 May 2014
Frost, J. M.
50e6d008-efba-4c42-80be-6b140afc8259
Sanz, S.
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Rajeshkumar, T.
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Pitak, M. B.
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Coles, S. J.
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Rajaraman, G.
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Wernsdorfer, W.
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Schnack, J.
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Lusby, P. J.
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Brechin, E. K.
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Frost, J. M., Sanz, S., Rajeshkumar, T., Pitak, M. B., Coles, S. J., Rajaraman, G., Wernsdorfer, W., Schnack, J., Lusby, P. J. and Brechin, E. K.
(2014)
A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks.
Dalton Transactions, 43 (28), .
(doi:10.1039/c4dt01469c).
Abstract
The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn-12(III)] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.
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Published date: 22 May 2014
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences
Identifiers
Local EPrints ID: 369316
URI: http://eprints.soton.ac.uk/id/eprint/369316
ISSN: 1477-9226
PURE UUID: 9d975b8f-c408-4165-8900-034b4bfd02d2
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Date deposited: 30 Sep 2014 13:36
Last modified: 15 Mar 2024 03:01
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Contributors
Author:
J. M. Frost
Author:
S. Sanz
Author:
T. Rajeshkumar
Author:
M. B. Pitak
Author:
G. Rajaraman
Author:
W. Wernsdorfer
Author:
J. Schnack
Author:
P. J. Lusby
Author:
E. K. Brechin
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