A three-compartment chemically-driven molecular information ratchet
A three-compartment chemically-driven molecular information ratchet
We describe a three-compartment rotaxane information ratchet in which the macrocycle can be directionally transported in either direction along an achiral (disregarding isotopic labeling) track. Chiral DMAP-based catalysts promote a benzoylation reaction that ratchets the displacement of the macrocycle, transporting it predominantly to a particular end compartment determined by the handedness of the catalyst.
8321-8323
Carlone, Armando
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Goldup, Stephen M.
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Lebrasseur, Nathalie
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Leigh, David A.
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Wilson, Adam
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23 April 2012
Carlone, Armando
c79c1bdb-e400-4182-ac40-8af5c0cbf846
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lebrasseur, Nathalie
e26275aa-f20f-4da3-902f-7808c027b949
Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
Wilson, Adam
31e51d38-f600-4b7d-9dad-87e48aeed55e
Carlone, Armando, Goldup, Stephen M., Lebrasseur, Nathalie, Leigh, David A. and Wilson, Adam
(2012)
A three-compartment chemically-driven molecular information ratchet.
Journal of the American Chemical Society, 134 (20), .
(doi:10.1021/ja302711z).
(PMID:22524156)
Abstract
We describe a three-compartment rotaxane information ratchet in which the macrocycle can be directionally transported in either direction along an achiral (disregarding isotopic labeling) track. Chiral DMAP-based catalysts promote a benzoylation reaction that ratchets the displacement of the macrocycle, transporting it predominantly to a particular end compartment determined by the handedness of the catalyst.
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Published date: 23 April 2012
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 370653
URI: http://eprints.soton.ac.uk/id/eprint/370653
ISSN: 0002-7863
PURE UUID: 8252fb83-ba0a-49eb-9358-ce51ead23f58
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Date deposited: 03 Nov 2014 13:13
Last modified: 14 Mar 2024 18:20
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Contributors
Author:
Armando Carlone
Author:
Nathalie Lebrasseur
Author:
David A. Leigh
Author:
Adam Wilson
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