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Cadiot–Chodkiewicz active template synthesis of rotaxanes and switchable molecular shuttles with weak intercomponent interactions

Cadiot–Chodkiewicz active template synthesis of rotaxanes and switchable molecular shuttles with weak intercomponent interactions
Cadiot–Chodkiewicz active template synthesis of rotaxanes and switchable molecular shuttles with weak intercomponent interactions
Weak interaction, switchable, rotaxane-based molecular shuttles, in which the positional fidelity of the macrocycle is conferred by a single hydrogen bond in each state, are constructed through the high-yielding and selective active template heterocoupling of different functionalized alkynes using the Cadiot–Chodkiewicz reaction
1433-7851
4392-4396
Berná, José
b5dcd6e7-4598-42ff-a3a2-728c4d49fc2d
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lee, Ai-Lan
df4cd6d7-08ae-498d-b9e7-26e3449155d3
Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
Symes, Mark D.
c4bdd59d-9323-425f-8bb6-55259c4b9551
Teobaldi, Gilberto
b842ef03-dd93-4b6c-946f-51a487c84d15
Zerbetto, Francesco
0d362331-135f-43c6-8de5-e16a52420289
Berná, José
b5dcd6e7-4598-42ff-a3a2-728c4d49fc2d
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lee, Ai-Lan
df4cd6d7-08ae-498d-b9e7-26e3449155d3
Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
Symes, Mark D.
c4bdd59d-9323-425f-8bb6-55259c4b9551
Teobaldi, Gilberto
b842ef03-dd93-4b6c-946f-51a487c84d15
Zerbetto, Francesco
0d362331-135f-43c6-8de5-e16a52420289

Berná, José, Goldup, Stephen M., Lee, Ai-Lan, Leigh, David A., Symes, Mark D., Teobaldi, Gilberto and Zerbetto, Francesco (2008) Cadiot–Chodkiewicz active template synthesis of rotaxanes and switchable molecular shuttles with weak intercomponent interactions. Angewandte Chemie International Edition, 47 (23), 4392-4396. (doi:10.1002/anie.200800891).

Record type: Article

Abstract

Weak interaction, switchable, rotaxane-based molecular shuttles, in which the positional fidelity of the macrocycle is conferred by a single hydrogen bond in each state, are constructed through the high-yielding and selective active template heterocoupling of different functionalized alkynes using the Cadiot–Chodkiewicz reaction

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More information

e-pub ahead of print date: 29 April 2008
Published date: 26 May 2008
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 370666
URI: http://eprints.soton.ac.uk/id/eprint/370666
ISSN: 1433-7851
PURE UUID: ec51f902-b04f-4b48-af07-855a2dee226c
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

Catalogue record

Date deposited: 03 Nov 2014 12:35
Last modified: 14 Mar 2024 18:20

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Contributors

Author: José Berná
Author: Ai-Lan Lee
Author: David A. Leigh
Author: Mark D. Symes
Author: Gilberto Teobaldi
Author: Francesco Zerbetto

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