Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands
Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands
The development of lanthanide “peptide” bundles from ?-amino acid functionalized 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands is described, using either Eu(III)- or Tb(III)-directed synthesis. These ligands form stable and luminescent 1:3 (Ln:L) stoichiometric complexes in CH3CN upon the addition of 0.33 equiv of Ln(III); the Tb(III) bundles, in particular, are highly luminescent with quantum yields of up to 70%.
1426-1439
Byrne, Joseph P.
2eeef5fe-8784-435f-98dd-c9c1635f2ebf
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
O’Brien, John E.
49a7df75-b3e3-476f-bab2-55715c96b8c9
Peacock, Robert D.
cf938797-c8b4-43f6-b49d-6af680d03e3c
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50
29 January 2015
Byrne, Joseph P.
2eeef5fe-8784-435f-98dd-c9c1635f2ebf
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
O’Brien, John E.
49a7df75-b3e3-476f-bab2-55715c96b8c9
Peacock, Robert D.
cf938797-c8b4-43f6-b49d-6af680d03e3c
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50
Byrne, Joseph P., Kitchen, Jonathan A., O’Brien, John E., Peacock, Robert D. and Gunnlaugsson, Thorfinnur
(2015)
Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands.
Inorganic Chemistry, 54 (4), .
(doi:10.1021/ic502384w).
Abstract
The development of lanthanide “peptide” bundles from ?-amino acid functionalized 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands is described, using either Eu(III)- or Tb(III)-directed synthesis. These ligands form stable and luminescent 1:3 (Ln:L) stoichiometric complexes in CH3CN upon the addition of 0.33 equiv of Ln(III); the Tb(III) bundles, in particular, are highly luminescent with quantum yields of up to 70%.
This record has no associated files available for download.
More information
e-pub ahead of print date: 29 January 2015
Published date: 29 January 2015
Organisations:
Chemistry, Faculty of Natural and Environmental Sciences, Organic Chemistry: SCF
Identifiers
Local EPrints ID: 377040
URI: http://eprints.soton.ac.uk/id/eprint/377040
ISSN: 0020-1669
PURE UUID: ebb11856-ac03-4737-a2ce-16be614221eb
Catalogue record
Date deposited: 14 May 2015 11:15
Last modified: 14 Mar 2024 19:55
Export record
Altmetrics
Contributors
Author:
Joseph P. Byrne
Author:
Jonathan A. Kitchen
Author:
John E. O’Brien
Author:
Robert D. Peacock
Author:
Thorfinnur Gunnlaugsson
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics