Modelling of the concentration–time relationship based on global diffusion-charge transfer parameters in a flow-by reactor with a 3D electrode


Nava, J.L., Sosa, E., Carreno, G., Ponce de Leon Albarran, C.A. and Oropeza, M.T. (2006) Modelling of the concentration–time relationship based on global diffusion-charge transfer parameters in a flow-by reactor with a 3D electrode. Electrochimica Acta, 51, (20), 4210-4217. (doi:10.1016/j.electacta.2005.12.002).

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Description/Abstract

A concentration versus time relationship model based on the isothermal diffusion-charge transfer mechanism was developed for a flow-by reactor with a three-dimensional (3D) reticulated vitreous carbon (RVC) electrode. The relationship was based on the effectiveness factor (η) which lead to the simulation of the concentration decay at different electrode polarisation conditions, i.e.−0.1,−0.3 and−0.59V versus SCE; the charge transfer process was used for the former and mix and a mass transport control was used for the latter. Charge transfer and mass transport parameters were estimated from experimental data using Electrochemical Impedance Spectroscopy (EIS) and Linear Voltammetry (LV) techniques, respectively.

Item Type: Article
ISSNs: 0013-4686 (print)
Related URLs:
Keywords: concentration–time relationship, copper; diffusion-charge transfer mechanism, effectiveness factor, flow-by reactor, mass transport, RVC, 3D electrode
Subjects: T Technology > TP Chemical technology
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Engineering Sciences
University Structure - Pre August 2011 > School of Engineering Sciences > Engineering Materials & Surface Engineering
ePrint ID: 39284
Date Deposited: 27 Jun 2006
Last Modified: 27 Mar 2014 18:24
URI: http://eprints.soton.ac.uk/id/eprint/39284

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