Supramolecular templating of hierarchically porous metal–organic frameworks
Supramolecular templating of hierarchically porous metal–organic frameworks
This tutorial review summarises recent advances in the direct supramolecular templating of metal–organic frameworks (MOFs) with hierarchical porosity across the micro- and mesoporous regimes. These are set against the important synthetic considerations that need to be addressed to ensure that strong interactions between the MOF precursors and a stable template assembly allow the highest chance of success. The article is grouped by template type and each category is illustrated with key examples and, where reported, an evaluation of their enhanced properties arising from the hierarchical structuring of the porous networks.
5431-5443
Bradshaw, Darren
7677b11e-1961-447e-b9ba-4847a74bd4dd
El-Hankari, Samir
553903b7-2f34-4dcd-bd0a-cb0014eb4139
Lupica Spagnolo, Lucia
18ffdc3d-d91d-4d51-9b58-ec908286ba1e
Bradshaw, Darren
7677b11e-1961-447e-b9ba-4847a74bd4dd
El-Hankari, Samir
553903b7-2f34-4dcd-bd0a-cb0014eb4139
Lupica Spagnolo, Lucia
18ffdc3d-d91d-4d51-9b58-ec908286ba1e
Bradshaw, Darren, El-Hankari, Samir and Lupica Spagnolo, Lucia
(2014)
Supramolecular templating of hierarchically porous metal–organic frameworks.
Chemical Society Reviews, 43 (16), .
(doi:10.1039/C4CS00127C).
Abstract
This tutorial review summarises recent advances in the direct supramolecular templating of metal–organic frameworks (MOFs) with hierarchical porosity across the micro- and mesoporous regimes. These are set against the important synthetic considerations that need to be addressed to ensure that strong interactions between the MOF precursors and a stable template assembly allow the highest chance of success. The article is grouped by template type and each category is illustrated with key examples and, where reported, an evaluation of their enhanced properties arising from the hierarchical structuring of the porous networks.
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e-pub ahead of print date: 9 May 2014
Organisations:
Organic Chemistry: SCF
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Local EPrints ID: 395464
URI: http://eprints.soton.ac.uk/id/eprint/395464
ISSN: 0306-0012
PURE UUID: be2586f7-a125-4bbe-8a6c-42d0a40ef22e
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Date deposited: 31 May 2016 10:18
Last modified: 15 Mar 2024 03:40
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Author:
Samir El-Hankari
Author:
Lucia Lupica Spagnolo
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