Developments in the chemistry of the hard early metals (Groups 1-6) with thioether, selenoether and telluroether ligands
Developments in the chemistry of the hard early metals (Groups 1-6) with thioether, selenoether and telluroether ligands
The coordination chemistry of neutral thio-, seleno- and telluroether ligands towards the hard s-block, f-block and higher oxidation state early d-block metals has developed significantly over the 15 or so years. This has revealed several hitherto unknown classes of complexes and new insights into the chemistries of these hard-soft metal-ligand combinations. This Perspective describes the synthetic routes used to access such complexes and draws out their key structural features and spectroscopic properties. Where appropriate, applications of these species are also highlighted, including their use as single source precursors for the chemical vapour deposition of semiconducting metal chalcogenide thin films and as pre-catalysts for olefin polymerisation reactions.
18393-18416
Chang, Yao-Pang
9516eba3-1424-411c-8f13-c564cae63407
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gill
37d35b11-40ce-48c5-a68e-f6ce04cd4037
14 December 2016
Chang, Yao-Pang
9516eba3-1424-411c-8f13-c564cae63407
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gill
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Chang, Yao-Pang, Levason, William and Reid, Gill
(2016)
Developments in the chemistry of the hard early metals (Groups 1-6) with thioether, selenoether and telluroether ligands.
Dalton Transactions, 2016 (45), .
(doi:10.1039/C6DT03409H).
Abstract
The coordination chemistry of neutral thio-, seleno- and telluroether ligands towards the hard s-block, f-block and higher oxidation state early d-block metals has developed significantly over the 15 or so years. This has revealed several hitherto unknown classes of complexes and new insights into the chemistries of these hard-soft metal-ligand combinations. This Perspective describes the synthetic routes used to access such complexes and draws out their key structural features and spectroscopic properties. Where appropriate, applications of these species are also highlighted, including their use as single source precursors for the chemical vapour deposition of semiconducting metal chalcogenide thin films and as pre-catalysts for olefin polymerisation reactions.
Text
Dalton_perspective_final 13_10_2016.pdf
- Accepted Manuscript
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Accepted/In Press date: 18 October 2016
e-pub ahead of print date: 19 October 2016
Published date: 14 December 2016
Organisations:
Faculty of Natural and Environmental Sciences
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Local EPrints ID: 405550
URI: http://eprints.soton.ac.uk/id/eprint/405550
ISSN: 0300-9246
PURE UUID: 6a8df0fe-b0bd-485f-aa59-33dd0992d2dd
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Date deposited: 07 Feb 2017 13:21
Last modified: 16 Mar 2024 02:44
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Author:
Yao-Pang Chang
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