Cyclometalation via carbon–fluorine bond activation induced by silver particles

Hayden P., Thomas, Wang, Yue-Ming, Coles, Simon, Horton, Peter, Marr, Andrew C and Saunders, Graham C. (2017) Cyclometalation via carbon–fluorine bond activation induced by silver particles. Organometallics, 36 (5), 960-963. (doi:10.1021/acs.organomet.6b00872).

Record type: Article

Abstract

On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbon—fluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].

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Marr-Saunders communication revised 22 Feb - Accepted Manuscript

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e-pub ahead of print date: 27 February 2017

Published date: 13 March 2017

Organisations: Chemistry Research Support

Identifiers

Local EPrints ID: 408422

URI: http://eprints.soton.ac.uk/id/eprint/408422

DOI: doi:10.1021/acs.organomet.6b00872

ISSN: 0276-7333

PURE UUID: 3963eaa1-1fa9-4e28-9eb8-0bb7dde15e43

ORCID for Simon Coles:

orcid.org/0000-0001-8414-9272

ORCID for Peter Horton:

orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 20 May 2017 04:03

Last modified: 16 Mar 2024 05:18

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Contributors

Author: Thomas Hayden P.

Author: Yue-Ming Wang

Author: Simon Coles

Author: Peter Horton

Author: Andrew C Marr

Author: Graham C. Saunders

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