Ring-closing metathesis of heteroatom-substituted dienes
Ring-closing metathesis of heteroatom-substituted dienes
The ring-closing metathesis (RCM) of dienes that contain at least one participating heteroatom-substituted olefin is reviewed (olefins substituted with O, N, S, P, Si, B, and halogen atoms will be considered). Efforts have been made to include as many relevant examples of RCM of heteroatom-substituted dienes as possible, but due to the increasing volume of research in this area, an exhaustive coverage is not intended. Attention has focussed on diene RCM reactions catalysed by ruthenium and molybdenum alkylidene complexes, although a brief discussion of some ring-closing reactions of titanium alkylidene species is provided. Other metathesis reactions such as enyne RCM, cross-metathesis and ROMP are not included.
enamide, cyclic enol ethers, enol ether, alpha-amino acrylamide, benzo-fused heterocycles, ring-closed metathesis, cross-coupling reactions, organic-synthesis, medium-sized rings, vinylsilane, heterocycles, ethers, olefin metathesis, functionalized olefins, nitrogen-containing, vinyl halide, polycyclic
705-736
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Satcharoen, Vachiraporn
bd72ee7e-2c8c-4508-ba2b-0135a46859bf
2006
Brown, Richard C.D.
21ce697a-7c3a-480e-919f-429a3d8550f5
Satcharoen, Vachiraporn
bd72ee7e-2c8c-4508-ba2b-0135a46859bf
Brown, Richard C.D. and Satcharoen, Vachiraporn
(2006)
Ring-closing metathesis of heteroatom-substituted dienes.
Heterocycles, 70, .
Abstract
The ring-closing metathesis (RCM) of dienes that contain at least one participating heteroatom-substituted olefin is reviewed (olefins substituted with O, N, S, P, Si, B, and halogen atoms will be considered). Efforts have been made to include as many relevant examples of RCM of heteroatom-substituted dienes as possible, but due to the increasing volume of research in this area, an exhaustive coverage is not intended. Attention has focussed on diene RCM reactions catalysed by ruthenium and molybdenum alkylidene complexes, although a brief discussion of some ring-closing reactions of titanium alkylidene species is provided. Other metathesis reactions such as enyne RCM, cross-metathesis and ROMP are not included.
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Published date: 2006
Keywords:
enamide, cyclic enol ethers, enol ether, alpha-amino acrylamide, benzo-fused heterocycles, ring-closed metathesis, cross-coupling reactions, organic-synthesis, medium-sized rings, vinylsilane, heterocycles, ethers, olefin metathesis, functionalized olefins, nitrogen-containing, vinyl halide, polycyclic
Identifiers
Local EPrints ID: 44156
URI: http://eprints.soton.ac.uk/id/eprint/44156
ISSN: 1881-0942
PURE UUID: 2374cf4a-7dcb-467c-9e77-589ededda7a8
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Date deposited: 19 Feb 2007
Last modified: 08 Jan 2022 02:45
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Author:
Vachiraporn Satcharoen
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