Ruthenium PCP-bis(phosphinite) pincer complexes
Bedford, R.B., Betham, M., Blake, M.E., Coles, S.J., Draper, S.M., Hursthouse, M.B. and Scully, P.N. (2006) Ruthenium PCP-bis(phosphinite) pincer complexes. Inorganica Chimica Acta, 359, (6), 1870-1878. (doi:10.1016/j.ica.2005.07.050).
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Description/Abstract
The reactions of [RuHCl(CO)(PPh3)(3)] with resorcinol bis(phosphinite) pincer ligands lead to complexes of the general formula [RuCl(PCP)(CO)(PPh3)]; the crystal structure of one example has been determined. The structures of the bulky resorcinol 2-methyl4,6-di-tert-butyl resorcinol and its mono-diisopropylphosphinite derivative were also determined. Reactions of [RuCl2(PPh3)(3)] with resorcinot bis(phosphinite) ligands yield complexes of the type [RuCl(PCP)(PPh3)], while the reaction of C6H-2-Me-4,6-'Bu-2-1,3-(OPPh2) with [RuHCl(CO)(PPh3)(3)] provides a PCP-pincer complex in which the ligand has undergone 2-methyl C-H activation.
| Item Type: | Article |
|---|---|
| ISSNs: | 0020-1693 (print) |
| Related URLs: | |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 44379 |
| Date Deposited: | 05 Mar 2007 |
| Last Modified: | 01 Jun 2011 11:51 |
| Contributors: | Bedford, R.B. (Author) Betham, M. (Author) Blake, M.E. (Author) Coles, S.J. (Author) Draper, S.M. (Author) Hursthouse, M.B. (Author) Scully, P.N. (Author) |
| Date: | 2006 |
| Status: | Published |
| Contact Email Address: | r.bedford@bristol.ac.uk |
| URI: | http://eprints.soton.ac.uk/id/eprint/44379 |
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