Triethyl ammonium salt of O,O'-bis(p-tolyl)dithiophosphate, [Et3NH](+)[(4-MeC6H4O)(2)PS2](-)

Bingham, A.L., Drake, J.E., Gurnani, C., Hursthouse, M.B., Light, M.E., Nirwan, M. and Ratnani, R. (2006) Triethyl ammonium salt of O,O'-bis(p-tolyl)dithiophosphate, [Et3NH](+)[(4-MeC6H4O)(2)PS2](-). Journal of Chemical Crystallography, 36 (10), 627-630. (doi:10.1007/s10870-006-9107-3).

Abstract

Triethyl ammonium Salt of O,O'-bis(p-tolyl)dithiophosphate and O,O'-bis(m-tolyl)dithiophosphate have been obtained by reaction of p- and m-cresol, respectively with P2S5 in toluene and have been characterized by elemental analysis, IR, H-1 and P-31 NMR spectroscopy. The molecular structure of O,O'-bis(p-tolyl)dithiophosphate has been determined. Crystal data: [Et3NH](+)[(4-MeC6H4O)(2)PS2](-): Monoclinic, P2(1)/c, a=15.2441(9) angstrom, b=10.415(2) angstrom, c=3.9726(9) angstrom, beta=91.709(7)degrees, V=2217.5(1)angstrom(-3), Z=4.

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Contributors

Author: M.E. Light

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