NMR methods of studying orientational order in the liquid crystalline and isotropic phases of mesogenic samples
Emsley, J.W. (2005) NMR methods of studying orientational order in the liquid crystalline and isotropic phases of mesogenic samples. Liquid Crystals, 32, (11-12), 1515-1524. (doi:10.1080/02678290500284512)
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Official URL: http://dx.doi.org/10.1080/02678290500284512
Description/Abstract
The understanding of how to describe the orientational order of the molecules in liquid crystalline phases, and in the isotropic phase formed by mesogens, has undergone considerable development in the past 25 years; this progress is reviewed. In parallel with the theoretical developments it has also been shown that NMR spectroscopy plays a unique role in the measurement of the orientational order of the molecules, and it is explained how biaxial ordering can be characterized for rigid molecules, and how the conformationally-dependent order parameters necessary for flexible molecules can be obtained.
| Item Type: | Article |
|---|---|
| ISSN: | 0267-8292 (print) |
| Uncontrolled Keywords: | molecular-field-theory, nuclear-magnetic-resonance, pretransitional behavior, nematic solvents, solute, nematogens, anthracene, deuterium, alignment, spectra |
| Related URLs: | http://dx.doi.org/10.1080/0267...0500284512 |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 44429 |
| URI: | http://eprints.soton.ac.uk/id/eprint/44429 |
| Deposited On: | 01 Mar 2007 |
| Last Modified: | 01 Jun 2011 12:52 |
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