NMR methods of studying orientational order in the liquid crystalline and isotropic phases of mesogenic samples

Emsley, J.W. (2005) NMR methods of studying orientational order in the liquid crystalline and isotropic phases of mesogenic samples. Liquid Crystals, 32, (11-12), 1515-1524. (doi:10.1080/02678290500284512)

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Official URL: http://dx.doi.org/10.1080/02678290500284512

Description/Abstract

The understanding of how to describe the orientational order of the molecules in liquid crystalline phases, and in the isotropic phase formed by mesogens, has undergone considerable development in the past 25 years; this progress is reviewed. In parallel with the theoretical developments it has also been shown that NMR spectroscopy plays a unique role in the measurement of the orientational order of the molecules, and it is explained how biaxial ordering can be characterized for rigid molecules, and how the conformationally-dependent order parameters necessary for flexible molecules can be obtained.

Item Type:Article
ISSN:0267-8292 (print)
Uncontrolled Keywords:molecular-field-theory, nuclear-magnetic-resonance, pretransitional behavior, nematic solvents, solute, nematogens, anthracene, deuterium, alignment, spectra
Related URLs:http://dx.doi.org/10.1080/0267...0500284512
Subjects:Q Science
Q Science > QD Chemistry
Divisions:University Structure - Pre August 2011 > School of Chemistry
ePrint ID:44429
URI:http://eprints.soton.ac.uk/id/eprint/44429
Deposited On:01 Mar 2007
Last Modified:01 Jun 2011 12:52

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