Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems


Eweka, E. I. and Kerridge, D. H. (2006) Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems. Solid State Ionics, 177, (15-16), 1245-1250. (doi:10.1016/j.ssi.2006.04.048).

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Description/Abstract

A number of salt eutectics have shown non-ideal electrical conductivity on melting and solidification, indicating some overlap between regions of 'solid-like' and 'melt-like' conductivities. Solidified eutectics showed much higher conductivities than expected from the values of the component salts, which is attributed to higher interfacial areas between the salt phases formed on solidification, with ionic transport being facilitated in these regions, which would have relatively high disorder.

Item Type: Article
ISSNs: 0167-2738 (print)
Related URLs:
Keywords: li2so4-li2co3 system, hypereutectic salt, mixtures
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 44436
Date Deposited: 01 Mar 2007
Last Modified: 27 Mar 2014 18:28
Contact Email Address: dk@cornrose.fsnet.co.uk
URI: http://eprints.soton.ac.uk/id/eprint/44436

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