Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems
Eweka, E. I. and Kerridge, D. H. (2006) Non-ideal change of electrical conductivity on solidification and remelting of salt eutectics 1. Oxyanion-based systems. Solid State Ionics, 177, (15-16), 1245-1250. (doi:10.1016/j.ssi.2006.04.048).
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Description/Abstract
A number of salt eutectics have shown non-ideal electrical conductivity on melting and solidification, indicating some overlap between regions of 'solid-like' and 'melt-like' conductivities. Solidified eutectics showed much higher conductivities than expected from the values of the component salts, which is attributed to higher interfacial areas between the salt phases formed on solidification, with ionic transport being facilitated in these regions, which would have relatively high disorder.
| Item Type: | Article |
|---|---|
| ISSNs: | 0167-2738 (print) |
| Related URLs: | |
| Keywords: | li2so4-li2co3 system, hypereutectic salt, mixtures |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 44436 |
| Date Deposited: | 01 Mar 2007 |
| Last Modified: | 01 Jun 2011 06:56 |
| Contributors: | Eweka, E. I. (Author) Kerridge, D. H. (Author) |
| Date: | 2006 |
| Status: | Published |
| Contact Email Address: | dk@cornrose.fsnet.co.uk |
| URI: | http://eprints.soton.ac.uk/id/eprint/44436 |
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