Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers

Levason, W., Ratnani, R., Reid, G. and Webster, M. (2006) Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers. Inorganica Chimica Acta, 359, (14), 4627-4630. (doi:10.1016/j.ica.2006.05.017).


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The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/j.ica.2006.05.017
ISSNs: 0020-1693 (print)
Related URLs:
Keywords: molybdenum, crown ether, crystal structure, isopolyanions transition-metal complexes, crystal-structure, spectroscopic characterization, sphere coordination, scandium(iii), macrocycles, products, acid
Subjects: Q Science
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 44483
Accepted Date and Publication Date:
Date Deposited: 02 Mar 2007
Last Modified: 31 Mar 2016 12:18

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