Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers
Levason, W., Ratnani, R., Reid, G. and Webster, M. (2006) Secondary coordination of dichlorodioxomolybdenum(VI) to crown ethers. Inorganica Chimica Acta, 359, (14), 4627-4630. (doi:10.1016/j.ica.2006.05.017).
Download
Full text not available from this repository.
Original Publication URL: http://dx.doi.org/10.1016/j.ica.2006.05.017
Description/Abstract
The reactions of MoO2Cl2 with 15-crown-5 and 18-crown-6 in ether solution produced crystals of [MoO2Cl2(H2O)(2)] center dot (15-crown-5) and [MoO2Cl2(H2O)(2)] center dot (H2O)(2) center dot (18-crown-6) due to adventitious water. Further hydrolysis lead to crystals of [(H3O) center dot (crown)](2)-[Mo6O19]. The structures of the three complexes are briefly discussed.
| Item Type: | Article |
|---|---|
| ISSNs: | 0020-1693 (print) |
| Related URLs: | |
| Keywords: | molybdenum, crown ether, crystal structure, isopolyanions transition-metal complexes, crystal-structure, spectroscopic characterization, sphere coordination, scandium(iii), macrocycles, products, acid |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 44483 |
| Date Deposited: | 02 Mar 2007 |
| Last Modified: | 01 Jun 2011 11:50 |
| Contributors: | Levason, W. (Author) Ratnani, R. (Author) Reid, G. (Author) Webster, M. (Author) |
| Date: | 2006 |
| Status: | Published |
| Contact Email Address: | ratnaniraju@rediffmail.com |
| URI: | http://eprints.soton.ac.uk/id/eprint/44483 |
Actions (login required)
 |
View Item |
