1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me)
Levason, W., Reid, G. and Webster, M. (2006) 1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me). Acta Crystallographica Section C: Crystal Structure Communications, 62, (7), O438-O440. (doi:10.1107/S0108270106015915).
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Description/Abstract
The structures of the compounds 1,2-bis(diphenylphosphino)-benzene, C30H24P2, [2-(diphenylphosphino)phenyl] methyl-diphenylphosphonium iodide, C31H27P2+center dot I-, and [2-(dimethylphosphino) phenyl]trimethylphosphonium iodide, C11H19P2+center dot I-, show that quaternization only occurs at one P centre and results in significantly shorter P-C bonds and larger C-P-C angles, consistent with the formal oxidation from P-III to P-V.
| Item Type: | Article |
|---|---|
| ISSNs: | 0108-2701 (print) |
| Related URLs: | |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 44485 |
| Date Deposited: | 05 Mar 2007 |
| Last Modified: | 02 Mar 2012 11:49 |
| Contributors: | Levason, W. (Author) Reid, G. (Author) Webster, M. (Author) |
| Date: | 2006 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/44485 |
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