Saraswat, K., Prasad, R.N., Ratnani, R., Drake, J.E., Hursthouse, M.B. and Light, M.E. (2006) Synthesis, spectroscopic characterization and structural studies of mixed ligand complexes of Sr(II) and Ba(II) with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones crystal structure of 2-HOC6H4C(O)C6H5. Inorganica Chimica Acta, 359 (4), 1291-1295. (doi:10.1016/j.ica.2005.06.079).
Abstract
Reactions of Sr(II) and Ba(II) chlorides with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones in 1:1:1 molar ratios have resulted in the formation of mixed ligand complexes of the type [MLL'(H2O)(2)] (M = Sr(II) or Ba(II); HL = 2-hydroxybenzophenone and HL' = salicylaldehyde, 2-hydroxyacetophenone, 2-hydroxypropiophenone, pentane2,4-dione, 1-phenylbutane-1,3-dione or 1,3-diphenylpropane-1,3-dione). These complexes have been characterized by elemental analyses, TLC, IR and H-1 NMR spectroscopy.
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