Synthesis, spectroscopic characterization and structural studies of mixed ligand complexes of Sr(II) and Ba(II) with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones crystal structure of 2-HOC6H4C(O)C6H5


Saraswat, K., Prasad, R.N., Ratnani, R., Drake, J.E., Hursthouse, M.B. and Light, M.E. (2006) Synthesis, spectroscopic characterization and structural studies of mixed ligand complexes of Sr(II) and Ba(II) with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones crystal structure of 2-HOC6H4C(O)C6H5. Inorganica Chimica Acta, 359, (4), 1291-1295. (doi:10.1016/j.ica.2005.06.079).

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Description/Abstract

Reactions of Sr(II) and Ba(II) chlorides with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones in 1:1:1 molar ratios have resulted in the formation of mixed ligand complexes of the type [MLL'(H2O)(2)] (M = Sr(II) or Ba(II); HL = 2-hydroxybenzophenone and HL' = salicylaldehyde, 2-hydroxyacetophenone, 2-hydroxypropiophenone, pentane2,4-dione, 1-phenylbutane-1,3-dione or 1,3-diphenylpropane-1,3-dione). These complexes have been characterized by elemental analyses, TLC, IR and H-1 NMR spectroscopy.

Item Type: Article
ISSNs: 0020-1693 (print)
Related URLs:
Keywords: mixed ligand complexes, strontium, barium, ir spectra, nmr spectra alkaline-earth metals, calcium(ii) complexes, molecular-structure, chelate compounds, infrared spectra, mg(ii), ca(ii), 2-hydroxyacetophenone, magnesium(ii), 5-bromosalicylaldehyde
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 44538
Date Deposited: 02 Mar 2007
Last Modified: 27 Mar 2014 18:29
URI: http://eprints.soton.ac.uk/id/eprint/44538

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