Synthesis, spectroscopic characterization and structural studies of mixed ligand complexes of Sr(II) and Ba(II) with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones crystal structure of 2-HOC6H4C(O)C6H5
Saraswat, K., Prasad, R.N., Ratnani, R., Drake, J.E., Hursthouse, M.B. and Light, M.E. (2006) Synthesis, spectroscopic characterization and structural studies of mixed ligand complexes of Sr(II) and Ba(II) with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones crystal structure of 2-HOC6H4C(O)C6H5. Inorganica Chimica Acta, 359, (4), 1291-1295. (doi:10.1016/j.ica.2005.06.079).
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Description/Abstract
Reactions of Sr(II) and Ba(II) chlorides with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or beta-diketones in 1:1:1 molar ratios have resulted in the formation of mixed ligand complexes of the type [MLL'(H2O)(2)] (M = Sr(II) or Ba(II); HL = 2-hydroxybenzophenone and HL' = salicylaldehyde, 2-hydroxyacetophenone, 2-hydroxypropiophenone, pentane2,4-dione, 1-phenylbutane-1,3-dione or 1,3-diphenylpropane-1,3-dione). These complexes have been characterized by elemental analyses, TLC, IR and H-1 NMR spectroscopy.
| Item Type: | Article |
|---|---|
| ISSNs: | 0020-1693 (print) |
| Related URLs: | |
| Keywords: | mixed ligand complexes, strontium, barium, ir spectra, nmr spectra alkaline-earth metals, calcium(ii) complexes, molecular-structure, chelate compounds, infrared spectra, mg(ii), ca(ii), 2-hydroxyacetophenone, magnesium(ii), 5-bromosalicylaldehyde |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 44538 |
| Date Deposited: | 02 Mar 2007 |
| Last Modified: | 01 Jun 2011 06:56 |
| Contributors: | Saraswat, K. (Author) Prasad, R.N. (Author) Ratnani, R. (Author) Drake, J.E. (Author) Hursthouse, M.B. (Author) Light, M.E. (Author) |
| Date: | 2006 |
| Status: | Published |
| Contact Email Address: | prasadraghunandan@yahoo.com |
| URI: | http://eprints.soton.ac.uk/id/eprint/44538 |
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