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A nonoxidic sol-gel route to titanium nitride and carbonitride films by primary amine condensation

A nonoxidic sol-gel route to titanium nitride and carbonitride films by primary amine condensation
A nonoxidic sol-gel route to titanium nitride and carbonitride films by primary amine condensation
A solution phase route to films of nanocrystalline titanium nitride and carbonitride is reported. Transamination of Ti(NMe2)4 with primary amines results in primary amide groups which can self condense forming alkylimide bridges. The use of controlled amounts of amine results in sols in tetrahydrofuran, these can be coated onto silica substrates via a dip coating method. Pyrolysis of these films under ammonia or nitrogen leads to TiN and Ti(C,N) respectively.
1016-1022
Jackson, Andrew W.
049d4dbf-e5c9-4b4a-b5ae-bd16cd1b923b
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Jackson, Andrew W.
049d4dbf-e5c9-4b4a-b5ae-bd16cd1b923b
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5

Jackson, Andrew W. and Hector, Andrew L. (2007) A nonoxidic sol-gel route to titanium nitride and carbonitride films by primary amine condensation. Journal of Materials Chemistry, 17 (10), 1016-1022. (doi:10.1039/b616067k).

Record type: Article

Abstract

A solution phase route to films of nanocrystalline titanium nitride and carbonitride is reported. Transamination of Ti(NMe2)4 with primary amines results in primary amide groups which can self condense forming alkylimide bridges. The use of controlled amounts of amine results in sols in tetrahydrofuran, these can be coated onto silica substrates via a dip coating method. Pyrolysis of these films under ammonia or nitrogen leads to TiN and Ti(C,N) respectively.

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Published date: 2007
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Local EPrints ID: 44621
URI: http://eprints.soton.ac.uk/id/eprint/44621
DOI: doi:10.1039/b616067k
PURE UUID: fc3467d5-fca9-4c33-9b8a-0765f4a4e461
ORCID for Andrew L. Hector: ORCID iD orcid.org/0000-0002-9964-2163

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Date deposited: 01 Mar 2007
Last modified: 16 Mar 2024 02:53

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Contributors

Author: Andrew W. Jackson
Author: Andrew L. Hector ORCID iD

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