On the similarity in catalytic activity of homogeneous and heterogeneous Cr(VI) catalysts in the decomposition of cyclohexyl hydroperoxide
Buijs, W., Raja, R., Thomas, J. M. and Wolters, H. (2003) On the similarity in catalytic activity of homogeneous and heterogeneous Cr(VI) catalysts in the decomposition of cyclohexyl hydroperoxide. Catalysis Letters, 91, (3-4), 253-259. (doi:10.1023/B:CATL.0000007162.32473.85).
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Description/Abstract
Pyridinium dichromate, chromium trioxide and CrAlPO-5 showed a very similar selectivity pattern in the decomposition of cyclohexyl hydroperoxide. CrAPO-5 turned out to be a real heterogeneous catalyst, most likely acting via a similar mechanism to the homogeneous catalysts. Molecular modeling indicates that heterolytic decomposition of the intermediate cyclohexyl peroxychromate ester yields cyclohexanone and H2CrO4 via a cyclic transition state.
| Item Type: | Article |
|---|---|
| ISSNs: | 1011-372X (print) |
| Related URLs: | |
| Keywords: | cyclohexane oxidation, chromium,cralpo-5, cyclohexyl hydroperoxide decomposition, molecular modeling, liquid-phase oxidations |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54165 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 25 Apr 2013 16:51 |
| Contributors: | Buijs, W. (Author) Raja, R. (Author) Thomas, J. M. (Author) Wolters, H. (Author) |
| Date: | 2003 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54165 |
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