Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl)
Alvarez, C.S., Garcia, F., Humphrey, S.M., Hopkins, A.D., Kowenicki, R.A., McPartin, M., Layfield, R.A., Raja, R., Rogers, M.C., Woods, A.D. and Wright, D.S. (2005) Highly selective epoxidation of styrene using a transition metal aluminium(III) complex containing the [MeAl(2-py)(3)](-) anion (2-py=2-pyridyl). Chemical Communications, (2), 198-200. (doi:10.1039/b413488e).
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Description/Abstract
The reactions of [MeAl(2-py)3Li·thf]( 1) with FeCl2 or Cp2Mn in toluene–thf give simple access to the Group 13–transition metal heterometallic complexes [{MeAl(2-py)3}2M][M = Fe ( 2), Mn ( 3)]; complex 2 has been shown to be a highly selective styrene epoxidation catalyst in air.
| Item Type: | Article |
|---|---|
| ISSNs: | 1359-7345 (print) |
| Related URLs: | |
| Keywords: | catalysts, cu,molecular-oxygen, h2o2, iron(ii), chemistry, spin, olefins, ligands, contact |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54190 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 01 Jun 2011 04:50 |
| Contributors: | Alvarez, C.S. (Author) Garcia, F. (Author) Humphrey, S.M. (Author) Hopkins, A.D. (Author) Kowenicki, R.A. (Author) McPartin, M. (Author) Layfield, R.A. (Author) Raja, R. (Author) Rogers, M.C. (Author) Woods, A.D. (Author) Wright, D.S. (Author) |
| Date: | 2005 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54190 |
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