Ring-closing metathesis of heteroatom-substituted dienes
Brown, R.C.D. and Satcharoen, V. (2006) Ring-closing metathesis of heteroatom-substituted dienes. Heterocycles, 70, 705-736.
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The ring-closing metathesis (RCM) of dienes that contain at least one participating heteroatom-substituted olefin is reviewed (olefins substituted with O, N, S, P, Si, B, and halogen atoms will be considered). Efforts have been made to include as many relevant examples of RCM of heteroatom-substituted dienes as possible, but due to the increasing volume of research in this area, an exhaustive coverage is not intended. Attention has focussed on diene RCM reactions catalysed by ruthenium and molybdenum alkylidene complexes, although a brief discussion of some ring-closing reactions of titanium alkylidene species is provided. Other metathesis reactions such as enyne RCM, cross-metathesis and ROMP are not included.
|Keywords:||enamide, cyclic enol ethers, enol ether, alpha-amino acrylamide, benzo-fused heterocycles,ring-closed metathesis, cross-coupling reactions, organic-synthesis, medium-sized rings, vinylsilane, heterocycles, ethers, olefin metathesis, functionalized olefins, nitrogen-containing, vinyl halide, , polycyclic|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||31 Jul 2008|
|Last Modified:||27 Mar 2014 18:37|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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