Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide
Aragoni, M.C., Arca, M., Crespo, M., Devillanova, F.A., Hursthouse, M.B., Huth, S.L., Isaia, F., Lippolis, V. and Verani, G. (2007) Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide. Crystengcomm, 9, (10), 873-878. (doi:10.1039/b708972d).
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Description/Abstract
The reactions between dpds and the phosphonodithioato and dithiophosphato NiII complexes [Ni(MeOpdt)2] (1), [Ni(EtOpdt)2] (2), and [Ni((EtO)2PS2)2] (3) yielded the novel coordination polymers ( 1·dpds), ( 2·dpts), and ( 3·dps), featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4-dipyridyldisulfide; dps, 4,4-dipyridylmonosulfide; dpts, 4,4-dipyridyltrisulfide).
| Item Type: | Article |
|---|---|
| ISSNs: | 1466-8033 (print) |
| Related URLs: | |
| Keywords: | bonds, chemistry, ligands,s-s, disulfide, cleavage, reactivity, , solids, framework |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54233 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 01 Jun 2011 04:49 |
| Contributors: | Aragoni, M.C. (Author) Arca, M. (Author) Crespo, M. (Author) Devillanova, F.A. (Author) Hursthouse, M.B. (Author) Huth, S.L. (Author) Isaia, F. (Author) Lippolis, V. (Author) Verani, G. (Author) |
| Date: | 2007 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54233 |
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