Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide


Aragoni, M.C., Arca, M., Crespo, M., Devillanova, F.A., Hursthouse, M.B., Huth, S.L., Isaia, F., Lippolis, V. and Verani, G. (2007) Predictable and unpredictable reactions between 4,4 '-dipyridyldisulfide and phosphonodithioato/dithiophosphato Ni-II complexes: novel coordination polymers and the unique example of 4,4 '-dipyridyltrisulfide. Crystengcomm, 9, (10), 873-878. (doi:10.1039/b708972d).

Download

Full text not available from this repository.

Original Publication URL: http://dx.doi.org/10.1039/b708972d

Description/Abstract

The reactions between dpds and the phosphonodithioato and dithiophosphato NiII complexes [Ni(MeOpdt)2] (1), [Ni(EtOpdt)2] (2), and [Ni((EtO)2PS2)2] (3) yielded the novel coordination polymers ( 1·dpds), ( 2·dpts), and ( 3·dps), featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4-dipyridyldisulfide; dps, 4,4-dipyridylmonosulfide; dpts, 4,4-dipyridyltrisulfide).

Item Type: Article
ISSNs: 1466-8033 (print)
Related URLs:
Keywords: bonds, chemistry, ligands,s-s, disulfide, cleavage, reactivity, , solids, framework
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 54233
Date Deposited: 31 Jul 2008
Last Modified: 27 Mar 2014 18:37
URI: http://eprints.soton.ac.uk/id/eprint/54233

Actions (login required)

View Item View Item