An unprecedented polyborate ester anion: X-ray diffraction studies on [1,8-C10H6(NMe2)(2)H][B5O6(OMe)(4)]
Beckett, M.A.C.C., Horton, P.N., Hursthouse, M.B. and Varma, K.S. (2007) An unprecedented polyborate ester anion: X-ray diffraction studies on [1,8-C10H6(NMe2)(2)H][B5O6(OMe)(4)]. Inorganic Chemistry, 46, (10), 3801-3803. (doi:10.1021/ic700433e).
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Original Publication URL: http://dx.doi.org/10.1021/ic700433e
Description/Abstract
The slow hydrolysis of B(OMe)3 in a CH2Cl2 solution in the presence of 1,8-C10H6(NMe2)2 (5:1 ratio) led to the formation of the novel isolated pentaborate ester anion [B5O6(OMe)4]-, which was characterized by a single-crystal X-ray diffraction study as the salt [1,8-C10H6(NMe2)2H][B5O6(OMe)4].
| Item Type: | Article |
|---|---|
| ISSNs: | 0020-1669 (print) |
| Related URLs: | |
| Keywords: | boric-acid, pentaborate, 1st examples, arylboronic acids |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54243 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 01 Jun 2011 07:03 |
| Contributors: | Beckett, M.A.C.C. (Author) Horton, P.N. (Author) Hursthouse, M.B. (Author) Varma, K.S. (Author) |
| Date: | 2007 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54243 |
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