4,4,6,6-tetrachloro-2-[(2,4-dimethylphenyl)sulfanyl]-N-[4-(2,2,4,4-tetra chloro-1,3,5,7,11-pentaaza-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphaspiro[5.5] undeca-1,3,5-trien7-yl)butyl]-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triaza-triphosphinin-2-amine


Coles, S.J., Davies, D.B., Hursthouse, M.B., Ibisoglu, H., Kilic, A. and Shaw, R.A. (2007) 4,4,6,6-tetrachloro-2-[(2,4-dimethylphenyl)sulfanyl]-N-[4-(2,2,4,4-tetra chloro-1,3,5,7,11-pentaaza-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphaspiro[5.5] undeca-1,3,5-trien7-yl)butyl]-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triaza-triphosphinin-2-amine. Acta Crystallographica Section E-Structure Reports Online, 63, (9), O3753-U2529. (doi:10.1107/S1600536807038962).

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Description/Abstract

Reaction of the spermidine-bridged cyclophosphazene compound (N3P3Cl5)spd(N3P3Cl4) (spd = spermidine residue) with 2,4-dimethylthiophenol results in substitution of the P-Cl bond at the bridgehead >P(NHR)Cl group to give the title compound, C15H25Cl8N9P6S. An N-H...N hydrogen bond helps to establish the packing.

Item Type: Article
ISSNs: 1600-5368 (print)
Related URLs:
Keywords: derivatives, spermidine, cyclophosphazenes, crystal, spiro, , spiransa,ansa dilemma
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 54273
Date Deposited: 31 Jul 2008
Last Modified: 27 Mar 2014 18:37
URI: http://eprints.soton.ac.uk/id/eprint/54273

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