4,4,6,6-tetrachloro-2-[(2,4-dimethylphenyl)sulfanyl]-N-[4-(2,2,4,4-tetra chloro-1,3,5,7,11-pentaaza-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphaspiro[5.5] undeca-1,3,5-trien7-yl)butyl]-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triaza-triphosphinin-2-amine
Coles, S.J., Davies, D.B., Hursthouse, M.B., Ibisoglu, H., Kilic, A. and Shaw, R.A. (2007) 4,4,6,6-tetrachloro-2-[(2,4-dimethylphenyl)sulfanyl]-N-[4-(2,2,4,4-tetra chloro-1,3,5,7,11-pentaaza-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphaspiro[5.5] undeca-1,3,5-trien7-yl)butyl]-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triaza-triphosphinin-2-amine. Acta Crystallographica Section E-Structure Reports Online, 63, (9), O3753-U2529. (doi:10.1107/S1600536807038962).
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Description/Abstract
Reaction of the spermidine-bridged cyclophosphazene compound (N3P3Cl5)spd(N3P3Cl4) (spd = spermidine residue) with 2,4-dimethylthiophenol results in substitution of the P-Cl bond at the bridgehead >P(NHR)Cl group to give the title compound, C15H25Cl8N9P6S. An N-H...N hydrogen bond helps to establish the packing.
| Item Type: | Article |
|---|---|
| ISSNs: | 1600-5368 (print) |
| Related URLs: | |
| Keywords: | derivatives, spermidine, cyclophosphazenes, crystal, spiro, , spiransa,ansa dilemma |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54273 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 02 Mar 2012 13:32 |
| Contributors: | Coles, S.J. (Author) Davies, D.B. (Author) Hursthouse, M.B. (Author) Ibisoglu, H. (Author) Kilic, A. (Author) Shaw, R.A. (Author) |
| Date: | 2007 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54273 |
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