Synthesis and spectroscopic characterization of dimethyl/di(n-butyl)tin(IV)bis(O,O '-ditolyl dithiophosphate) complexes. Crystal structures of Me2Sn[S2P(OC6H4Me-o)(2)](2) and n-Bu2Sn[S2P(OC6H4Me-o)(2)](2)


Drake, J.E., Gurnani, C., Hursthouse, M.B., Light, M.E., Nirwan, M. and Ratnani, R. (2007) Synthesis and spectroscopic characterization of dimethyl/di(n-butyl)tin(IV)bis(O,O '-ditolyl dithiophosphate) complexes. Crystal structures of Me2Sn[S2P(OC6H4Me-o)(2)](2) and n-Bu2Sn[S2P(OC6H4Me-o)(2)](2). Applied Organometallic Chemistry, 21, (7), 539-544. (doi:10.1002/aoc.1265).

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Original Publication URL: http://dx.doi.org/10.1002/aoc.1265

Description/Abstract

Organotin(IV) complexes of the type, R2Sn[S2P(OR)2]2 (where R = Me, n-Bu and R = o-, m-, p-C6H4Me) have been obtained by the reaction of Me2SnCl2 or n-Bu2SnCl2 with ammonium salts of the corresponding O,O-ditolyl dithiophosphates on stirring in benzene and have been characterized by elemental analysis and IR, 1H, 13C, 31P and 119Sn NMR spectroscopy. Trends in data are discussed. The crystal structures of Me2Sn[S2P(OC6H4Me-o)2]2 and n-Bu2Sn[S2P(OC6H4Me-o)2]2 are reported. The environment around the tin atom in both molecules may be described as having skew-trapezoid bipyramidal geometry.

Item Type: Article
ISSNs: 0268-2605 (print)
Related URLs:
Keywords: oxy, di(o-, tin, bis(dithiophosphate) esters, m- or p-tolyl) dithiophosphates, bicyclic dimer, dialkyldithiophosphates, molecular-structures, crystal structures, phosphorus-acid-derivatives, held, , nmr spectroscopy, triethyl ammonium-salt, x-ray, supramolecular associations,organotin(iv) complexes
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 54285
Date Deposited: 31 Jul 2008
Last Modified: 27 Mar 2014 18:37
URI: http://eprints.soton.ac.uk/id/eprint/54285

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