Analytical theory of gamma-encoded double-quantum recoupling sequences in solid-state nuclear magnetic resonance


Pileio, G., Concistre, M., McLean, N., Gansmulller, A., Brown, R.C.D. and Levitt, M.H. (2007) Analytical theory of gamma-encoded double-quantum recoupling sequences in solid-state nuclear magnetic resonance. Journal of Magnetic Resonance, 186, (1), 65-74. (doi:10.1016/j.jmr.2007.01.009).

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Description/Abstract

Many important double-quantum recoupling techniques in solid-state NMR are classified as being γ-encoded. This means that the phase of the double-quantum effective Hamiltonian, but not its amplitude, depends on the third Euler angle defining the orientation of the molecular spin system in the frame of the magic-angle-spinning rotor. In this paper, we provide closed analytical solutions for the dependence of the powder-average double-quantum-filtered signal on the recoupling times, within the average Hamiltonian approximation for γ-encoded pulse sequences. The validity of the analytical solutions is tested by numerical simulations. The internuclear distance in a 13C2-labelled retinal is estimated by fitting the analytical curves to experimental double-quantum data.

Item Type: Article
ISSNs: 1090-7807 (print)
Related URLs:
Keywords: angle-spinning nmr, , symmetry, fresnel, , polarization transfer, homonuclear rotary resonance, cross-polarization, magic-angle-spinning, symmetry-based recoupling, proton-enhanced nmr, principles, solid-state nmr,recoupling, pulse sequence, rotating solids, spectroscopy, dilute spins
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 54360
Date Deposited: 31 Jul 2008
Last Modified: 27 Mar 2014 18:37
URI: http://eprints.soton.ac.uk/id/eprint/54360

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