Analytical theory of gamma-encoded double-quantum recoupling sequences in solid-state nuclear magnetic resonance
Pileio, G., Concistre, M., McLean, N., Gansmulller, A., Brown, R.C.D. and Levitt, M.H. (2007) Analytical theory of gamma-encoded double-quantum recoupling sequences in solid-state nuclear magnetic resonance. Journal of Magnetic Resonance, 186, (1), 65-74. (doi:10.1016/j.jmr.2007.01.009).
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Description/Abstract
Many important double-quantum recoupling techniques in solid-state NMR are classified as being γ-encoded. This means that the phase of the double-quantum effective Hamiltonian, but not its amplitude, depends on the third Euler angle defining the orientation of the molecular spin system in the frame of the magic-angle-spinning rotor. In this paper, we provide closed analytical solutions for the dependence of the powder-average double-quantum-filtered signal on the recoupling times, within the average Hamiltonian approximation for γ-encoded pulse sequences. The validity of the analytical solutions is tested by numerical simulations. The internuclear distance in a 13C2-labelled retinal is estimated by fitting the analytical curves to experimental double-quantum data.
| Item Type: | Article |
|---|---|
| ISSNs: | 1090-7807 (print) |
| Related URLs: | |
| Keywords: | angle-spinning nmr, , symmetry, fresnel, , polarization transfer, homonuclear rotary resonance, cross-polarization, magic-angle-spinning, symmetry-based recoupling, proton-enhanced nmr, principles, solid-state nmr,recoupling, pulse sequence, rotating solids, spectroscopy, dilute spins |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54360 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 23 Jul 2012 10:45 |
| Contributors: | Pileio, G. (Author) Concistre, M. (Author) McLean, N. (Author) Gansmulller, A. (Author) Brown, R.C.D. (Author) Levitt, M.H. (Author) |
| Date: | 2007 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54360 |
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