A high-performance selective oxidation system for the facile production of fine chemicals
Raja, R., Thomas, J.M., Greenhill-Hooper, M. and Doukova, V. (2007) A high-performance selective oxidation system for the facile production of fine chemicals. Chemical Communications, (19), 1924-1926. (doi:10.1039/b618090f).
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Description/Abstract
MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.
| Item Type: | Article |
|---|---|
| ISSNs: | 1359-7345 (print) |
| Related URLs: | |
| Keywords: | site heterogeneous catalysts, decomposition, , cyclohexane, alcohols, molecular-oxygen, insight |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 54373 |
| Date Deposited: | 31 Jul 2008 |
| Last Modified: | 01 Jun 2011 02:34 |
| Contributors: | Raja, R. (Author) Thomas, J.M. (Author) Greenhill-Hooper, M. (Author) Doukova, V. (Author) |
| Date: | 2007 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/54373 |
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