A high-performance selective oxidation system for the facile production of fine chemicals
Raja, R., Thomas, J.M., Greenhill-Hooper, M. and Doukova, V. (2007) A high-performance selective oxidation system for the facile production of fine chemicals. Chemical Communications, (19), 1924-1926. (doi:10.1039/b618090f).
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MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.
|Keywords:||site heterogeneous catalysts, decomposition, , cyclohexane, alcohols, molecular-oxygen, insight|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||31 Jul 2008|
|Last Modified:||01 Jun 2011 02:34|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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