A high-performance selective oxidation system for the facile production of fine chemicals


Raja, R., Thomas, J.M., Greenhill-Hooper, M. and Doukova, V. (2007) A high-performance selective oxidation system for the facile production of fine chemicals. Chemical Communications, (19), 1924-1926. (doi:10.1039/b618090f).

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Original Publication URL: http://dx.doi.org/10.1039/b618090f

Description/Abstract

MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.

Item Type: Article
ISSNs: 1359-7345 (print)
Related URLs:
Keywords: site heterogeneous catalysts, decomposition, , cyclohexane, alcohols, molecular-oxygen, insight
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 54373
Date Deposited: 31 Jul 2008
Last Modified: 27 Mar 2014 18:37
URI: http://eprints.soton.ac.uk/id/eprint/54373

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