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The regiochemistry of zirconacycle elaboration

The regiochemistry of zirconacycle elaboration
The regiochemistry of zirconacycle elaboration
The regioselectivity of insertion of carbenoids into a variety of unsymmetrical zirconacyclopentanes is reported. For comparison the regioselectivities of isonitrile insertion and protonation have also been determined.
copper chloride, carbenoid, complexes, metallacycle transfer, convenient method, metal-promoted cyclization, diene cyclization, zirconocene, selective formation, zirconium chemistry, insertion, bond formation reaction
0040-4020
11686-11701
Thomas, Emma
69f1cb1a-8550-4194-9904-67f6d9535ff1
Dixon, Sally
943160fc-1b70-4c29-b2e3-b7785cee8a0c
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Thomas, Emma
69f1cb1a-8550-4194-9904-67f6d9535ff1
Dixon, Sally
943160fc-1b70-4c29-b2e3-b7785cee8a0c
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b

Thomas, Emma, Dixon, Sally and Whitby, Richard J. (2007) The regiochemistry of zirconacycle elaboration. Tetrahedron, 63 (47), 11686-11701. (doi:10.1016/j.tet.2007.08.105).

Record type: Article

Abstract

The regioselectivity of insertion of carbenoids into a variety of unsymmetrical zirconacyclopentanes is reported. For comparison the regioselectivities of isonitrile insertion and protonation have also been determined.

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More information

Published date: 19 November 2007
Keywords: copper chloride, carbenoid, complexes, metallacycle transfer, convenient method, metal-promoted cyclization, diene cyclization, zirconocene, selective formation, zirconium chemistry, insertion, bond formation reaction

Identifiers

Local EPrints ID: 54396
URI: http://eprints.soton.ac.uk/id/eprint/54396
ISSN: 0040-4020
PURE UUID: d55995f6-bb29-4aa2-b214-822292807af1
ORCID for Sally Dixon: ORCID iD orcid.org/0000-0003-2219-3635
ORCID for Richard J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

Catalogue record

Date deposited: 31 Jul 2008
Last modified: 16 Mar 2024 03:24

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Contributors

Author: Emma Thomas
Author: Sally Dixon ORCID iD

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