On the highly stereoselective addition of lithio-acetylides to alpha-hydroxy-ketones


Dunford, D., Guyader, M., Jones, S., Knight, D.W., Hursthouse, M.B. and Coles, S.J. (2008) On the highly stereoselective addition of lithio-acetylides to alpha-hydroxy-ketones. Tetrahedron Letters, 49, (14), 2240-2242. (doi:10.1016/j.tetlet.2008.02.032).

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Description/Abstract

Addition of 2 equiv of a lithio-acetylide to an unprotected α-hydroxy ketone is extremely stereoselective in examples where the two ketone substituents are relatively large.

Item Type: Article
ISSNs: 0040-4039 (print)
Related URLs:
Keywords: 5-endo-dig cyclizations, beta-iodofurans
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 54445
Date Deposited: 05 Aug 2008
Last Modified: 27 Mar 2014 18:37
URI: http://eprints.soton.ac.uk/id/eprint/54445

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