A dynamic performance model for redox-flow batteries involving soluble species
Shah, A.A., Watt-Smith, M.J. and Walsh, F.C. (2008) A dynamic performance model for redox-flow batteries involving soluble species. Electrochimica Acta, 53, (27), 8087-8100. (doi:10.1016/j.electacta.2008.05.067).
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Description/Abstract
A transient modelling framework for a vanadium redox-flow battery (RFB) is developed and experiments covering a range of vanadium concentration and electrolyte flow rate are conducted. The two-dimensional model is based on a comprehensive description of mass, charge and momentum transport and conservation, and is combined with a global kinetic model for reactions involving vanadium species. The model is validated against the experimental data and is used to study the effects of variations in concentration, electrolyte flow rate and electrode porosity. Extensions to the model and future work are suggested.
| Item Type: | Article |
|---|---|
| ISSNs: | 0013-4686 (print) |
| Related URLs: | |
| Keywords: | redox-flow battery, vanadium redox cells, energy storage, energy conversion, mathematical model |
| Subjects: | T Technology > TP Chemical technology T Technology > TK Electrical engineering. Electronics Nuclear engineering Q Science > QA Mathematics |
| Divisions: | University Structure - Pre August 2011 > School of Engineering Sciences > Thermofluids and Superconductivity |
| Item ID: | 65090 |
| Date Deposited: | 02 Feb 2009 |
| Last Modified: | 08 Jun 2012 12:50 |
| Contributors: | Shah, A.A. (Author) Watt-Smith, M.J. (Author) Walsh, F.C. (Author) |
| Date: | 15 November 2008 |
| Status: | Published |
| Contact Email Address: | A.Shah@soton.ac.uk |
| URI: | http://eprints.soton.ac.uk/id/eprint/65090 |
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