A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II). Part IX: Electrode and electrolyte conditioning with hydrogen peroxide
Collins, John, Li, Xiaohong, Pletcher, Derek, Tangirala, Ravichandra, Stratton-Campbell, Duncan, Walsh, Frank C and Zhang, Caiping (2009) A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II). Part IX: Electrode and electrolyte conditioning with hydrogen peroxide. Journal of Power Sources, 195, (9), 2975-2978. (doi:10.1016/j.jpowsour.2009.10.109).
Extended cycling of a soluble lead acid battery can lead to problems due to an imbalance in the coulombic efficiency leading to deposits of Pb and PbO2 on the electrodes. Periodic addition of hydrogen peroxide to the electrolyte of the soluble lead acid flow battery largely overcomes several operational problems seen during extended cycling, using a 10 cm×10cm parallel plate flow cell. It is shown that this treatment greatly extends the number of cycles that can be achieved with a reasonable energy-, voltage-, and charge efficiency of 54–66%, 71%, and 77–91%.
|Digital Object Identifier (DOI):||doi:10.1016/j.jpowsour.2009.10.109|
|Keywords:||Energy storage Flow battery Lead Lead dioxide Lead ions Peroxide ions|
|Subjects:||T Technology > TP Chemical technology
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Engineering Sciences > Engineering Materials & Surface Engineering
|Date Deposited:||12 Jan 2010|
|Last Modified:||06 Aug 2015 02:56|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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