4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one
4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one
The title compound, C20H16O7, is an intermediate in the total synthesis of (+/-)-asarinin. The molecular structure contains four chiral centres and crystallizes as two independent molecules. The chirality of the two molecules is the same, but they adopt different conformations. The compound is enantiomeric, with the second enantiomer arising from the centrosymmetric nature of the space group.
o544-o546
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
1 June 2001
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, S. J. and Hursthouse, M. B.
(2001)
4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one.
Acta Crystallographica Section E: Structure Reports Online, 57 (6), .
(doi:10.1107/S1600536801007437).
Abstract
The title compound, C20H16O7, is an intermediate in the total synthesis of (+/-)-asarinin. The molecular structure contains four chiral centres and crystallizes as two independent molecules. The chirality of the two molecules is the same, but they adopt different conformations. The compound is enantiomeric, with the second enantiomer arising from the centrosymmetric nature of the space group.
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Published date: 1 June 2001
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Local EPrints ID: 19456
URI: http://eprints.soton.ac.uk/id/eprint/19456
PURE UUID: 16b649e9-c4dc-4607-b6e2-08ad92976316
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Date deposited: 15 Feb 2006
Last modified: 16 Mar 2024 03:05
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