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Bis(triphenylstannyl)borate toluene solvate

Bis(triphenylstannyl)borate toluene solvate
Bis(triphenylstannyl)borate toluene solvate
The title compound, [Sn-2(C6H5)(6)(BHO3)].C7H8 or (Ph3SnO)(2)-B(OH).C7H8, is an unexpected diester produced during an attempted recrystallization of (Ph3Sn)(3)B3O3. A planar central B atom is coordinated to two Ph3Sn groups through ester linkages, and to a hydroxide group.
acids
m65-m67
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hibbs, D. E.
bcaa2c3a-d480-46a7-b65a-50b8ee172f73
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, M. A.
42da77d2-c5b1-4050-8e68-42c0cccb82fb
Owen, P.
567f4295-4870-4af2-9341-d05316786a9f
Varma, K. S.
1c1be808-50a2-4386-8159-c0dbcbf641cd
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hibbs, D. E.
bcaa2c3a-d480-46a7-b65a-50b8ee172f73
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Beckett, M. A.
42da77d2-c5b1-4050-8e68-42c0cccb82fb
Owen, P.
567f4295-4870-4af2-9341-d05316786a9f
Varma, K. S.
1c1be808-50a2-4386-8159-c0dbcbf641cd

Coles, S. J., Hibbs, D. E., Hursthouse, M. B., Beckett, M. A., Owen, P. and Varma, K. S. (2002) Bis(triphenylstannyl)borate toluene solvate. Acta Crystallographica Section E: Crystallographic Communications, 58 (2), m65-m67. (doi:10.1107/S1600536802001642).

Record type: Article

Abstract

The title compound, [Sn-2(C6H5)(6)(BHO3)].C7H8 or (Ph3SnO)(2)-B(OH).C7H8, is an unexpected diester produced during an attempted recrystallization of (Ph3Sn)(3)B3O3. A planar central B atom is coordinated to two Ph3Sn groups through ester linkages, and to a hydroxide group.

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More information

Published date: 1 February 2002
Keywords: acids
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Identifiers

Local EPrints ID: 19703
URI: http://eprints.soton.ac.uk/id/eprint/19703
DOI: doi:10.1107/S1600536802001642
PURE UUID: e8e7c953-cd9c-44a2-bbf6-c1bcd5a05783
ORCID for S. J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 16 Feb 2006
Last modified: 16 Mar 2024 03:05

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Contributors

Author: S. J. Coles ORCID iD
Author: D. E. Hibbs
Author: M. B. Hursthouse
Author: M. A. Beckett
Author: P. Owen
Author: K. S. Varma

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