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Dabconium orthofluoroberyllate hemihydrate

Dabconium orthofluoroberyllate hemihydrate
Dabconium orthofluoroberyllate hemihydrate
Alternating C6H14N22+ and [BeF4](2-) units within the ac plane of 1,4-diazoniabicyclo[2.2.2]octane tetrafluoroberyllium hemihydrate, (C6H14N2)[BeF4].0.5H(2)O, combine to form double chains via hydrogen bonding. These double chains connect through bifurcated hydrogen bonds to water molecules, which lie on twofold axes, producing a two-dimensional sheet. Very weak hydrogen-bond interactions, along the b axis, join the sheets to produce a three-dimensional network.
2053-2296
m407-m408
Gerrard, L. A.
e3794da7-3745-4020-b670-67491e1adaf1
Weller, M. T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4
Gerrard, L. A.
e3794da7-3745-4020-b670-67491e1adaf1
Weller, M. T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4

Gerrard, L. A. and Weller, M. T. (2002) Dabconium orthofluoroberyllate hemihydrate. Acta Crystallographica Section C: Structural Chemistry, 58 (7), m407-m408. (doi:10.1107/S0108270102009654).

Record type: Article

Abstract

Alternating C6H14N22+ and [BeF4](2-) units within the ac plane of 1,4-diazoniabicyclo[2.2.2]octane tetrafluoroberyllium hemihydrate, (C6H14N2)[BeF4].0.5H(2)O, combine to form double chains via hydrogen bonding. These double chains connect through bifurcated hydrogen bonds to water molecules, which lie on twofold axes, producing a two-dimensional sheet. Very weak hydrogen-bond interactions, along the b axis, join the sheets to produce a three-dimensional network.

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More information

Published date: 1 July 2002

Identifiers

Local EPrints ID: 19747
URI: http://eprints.soton.ac.uk/id/eprint/19747
ISSN: 2053-2296
PURE UUID: 32a7d355-e76c-4266-9c11-f326e4a3e210

Catalogue record

Date deposited: 16 Feb 2006
Last modified: 15 Mar 2024 06:18

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Contributors

Author: L. A. Gerrard
Author: M. T. Weller

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