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Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones

Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones
Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones
Silylated methylenecyclopropyl hydrazones on treatment with BF3.Et2O cyclise to give heterocyclic products involving a novel sequence of hydride and silyl shifts via a series of increasingly stable cationic intermediates.
cycloaddition, aldehydes, acylhydrazones, additions, ketones
1359-7345
2552-2553
Patient, L.
ce95f606-faf0-477e-9129-ed2b85bb9c6c
Berry, M. B.
8a21d139-9bf7-45a4-a32e-be4a4b3282b5
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
Patient, L.
ce95f606-faf0-477e-9129-ed2b85bb9c6c
Berry, M. B.
8a21d139-9bf7-45a4-a32e-be4a4b3282b5
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8

Patient, L., Berry, M. B., Coles, S. J., Hursthouse, M. B. and Kilburn, J. D. (2003) Lewis acid mediated cyclisations of silylated methylenecyclopropyl hydrazones. Chemical Communications, (20), 2552-2553. (doi:10.1039/b306636c).

Record type: Article

Abstract

Silylated methylenecyclopropyl hydrazones on treatment with BF3.Et2O cyclise to give heterocyclic products involving a novel sequence of hydride and silyl shifts via a series of increasingly stable cationic intermediates.

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More information

Published date: 2003
Keywords: cycloaddition, aldehydes, acylhydrazones, additions, ketones
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Identifiers

Local EPrints ID: 20059
URI: http://eprints.soton.ac.uk/id/eprint/20059
DOI: doi:10.1039/b306636c
ISSN: 1359-7345
PURE UUID: ce6e0da8-2f15-48e5-bb9b-6f0661c8f40e
ORCID for S. J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 22 Feb 2006
Last modified: 16 Mar 2024 03:05

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Contributors

Author: L. Patient
Author: M. B. Berry
Author: S. J. Coles ORCID iD
Author: M. B. Hursthouse
Author: J. D. Kilburn

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