Ferrocenyl-substituted fluorescent anthracenes and anthraquinones
Ferrocenyl-substituted fluorescent anthracenes and anthraquinones
The synthesis of a range of ferrocene-substituted ethynylanthracenes and 1,1'-(bis-(2-ethenylanthraquinoyl)ferrocene has been achieved. The synthesis relies on the production of ferrocenylanthraquinones as key precursors. The products were obtained in the reactions of ferrocenylanthraquinones with phenyl ethynyl lithium or trimethylsilylethynyllithium followed by reduction with tin chloride. The key products such as 1- and 2-ferrocenyl(9,10-bis-phenylethynyl)anthracenes have been characterised by X-ray single crystal diffraction.
ferrocene, anthraquinone, anthracene
electrochemical sensor, derivatives, binding, complexation, recognition, systems, chemiluminescence, electrodes, peroxide, receptor
467-472
Butler, I. R.
d8a1fc6e-b2be-42fe-b655-c65b803c8903
Callabero, A. G.
f55a55bc-bd90-481f-8238-c0c3bca813d7
Kelly, G. A.
9d9f7902-cf3c-4e19-9942-7036d4660c64
Amey, J. R.
5b8d42df-fc26-45ed-8574-9138a96bb4e5
Kraemer, T.
740e39cd-0026-489c-9e37-419c1bb63bdd
Thomas, D. A.
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Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Gelbrich, T.
42309d69-eaf1-4bb7-ba2e-db61f338e370
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
12 January 2004
Butler, I. R.
d8a1fc6e-b2be-42fe-b655-c65b803c8903
Callabero, A. G.
f55a55bc-bd90-481f-8238-c0c3bca813d7
Kelly, G. A.
9d9f7902-cf3c-4e19-9942-7036d4660c64
Amey, J. R.
5b8d42df-fc26-45ed-8574-9138a96bb4e5
Kraemer, T.
740e39cd-0026-489c-9e37-419c1bb63bdd
Thomas, D. A.
b81b28b6-1c3d-4527-89df-e57b347f22dc
Light, M. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Gelbrich, T.
42309d69-eaf1-4bb7-ba2e-db61f338e370
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Butler, I. R., Callabero, A. G., Kelly, G. A., Amey, J. R., Kraemer, T., Thomas, D. A., Light, M. E., Gelbrich, T. and Coles, S. J.
(2004)
Ferrocenyl-substituted fluorescent anthracenes and anthraquinones.
Tetrahedron Letters, 45 (3), .
(doi:10.1016/j.tetlet.2003.11.013).
Abstract
The synthesis of a range of ferrocene-substituted ethynylanthracenes and 1,1'-(bis-(2-ethenylanthraquinoyl)ferrocene has been achieved. The synthesis relies on the production of ferrocenylanthraquinones as key precursors. The products were obtained in the reactions of ferrocenylanthraquinones with phenyl ethynyl lithium or trimethylsilylethynyllithium followed by reduction with tin chloride. The key products such as 1- and 2-ferrocenyl(9,10-bis-phenylethynyl)anthracenes have been characterised by X-ray single crystal diffraction.
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Published date: 12 January 2004
Keywords:
ferrocene, anthraquinone, anthracene
electrochemical sensor, derivatives, binding, complexation, recognition, systems, chemiluminescence, electrodes, peroxide, receptor
Identifiers
Local EPrints ID: 20153
URI: http://eprints.soton.ac.uk/id/eprint/20153
ISSN: 0040-4039
PURE UUID: 82d9e7dc-61de-4b89-9274-feb4f2af4642
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Date deposited: 20 Feb 2006
Last modified: 16 Mar 2024 03:05
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Contributors
Author:
I. R. Butler
Author:
A. G. Callabero
Author:
G. A. Kelly
Author:
J. R. Amey
Author:
T. Kraemer
Author:
D. A. Thomas
Author:
T. Gelbrich
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