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An experimental study of the interaction of basaltic riverine particulate material and seawater

An experimental study of the interaction of basaltic riverine particulate material and seawater
An experimental study of the interaction of basaltic riverine particulate material and seawater
The riverine transport of elements from land to ocean is an integral flux for many element cycles and an important climate regulating process over geological timescales. This flux consists of both dissolved and particulate material. The world’s rivers are estimated to transport between 16.6 and 30 Gt yr?1 of particulate material, considerably higher than the dissolved flux of ?1 Gt yr?1. Therefore, the dissolution of particulate material upon arrival in estuaries and coastal waters may be a significant flux for many elements. Here we assess the role of riverine particulate material dissolution in seawater with closed-system experiments using riverine bedload material and estuarine sediment from western Iceland mixed with open ocean seawater. Both particulate materials significantly changed the elemental concentrations of the surrounding water with substantial increases in Si concentrations indicative of silicate dissolution. Seawater in contact with bedload material shows considerable enrichment of Ca, Mg, Mn, and Ni, while Li and K concentrations decrease. Moreover, the 87Sr/86Sr of seawater decreases with time with little change in Sr concentrations, indicative of a significant two-way flux between the solid and fluid phases. Mass balance calculations indicate that 3% of the Sr contained in the original riverine bedload was released during 9 months of reaction. In contrast, the estuarine material has a negligible effect on seawater 87Sr/86Sr and transition metal concentrations, suggesting that these reactions occur when particulate material first arrives into coastal waters. Solubility calculations performed using the PHREEQC computer code confirm that primary minerals are undersaturated, while secondary minerals such as kaolinite are oversaturated in the reacted fluids. These results demonstrate that riverine transported basaltic particulate material can significantly alter the composition of seawater, although the total concentrations of many major elements in seawater are regulated by the formation of secondary phases. This behavior has important implications for nutrient supply to coastal waters and the isotopic mass balance of several elements in the oceans
0016-7037
108-120
Jones, Morgan T.
cf1c7a87-0578-4e4b-8708-a22a5b9e7df4
Pearce, Christopher R.
3d683112-72dc-444f-ae06-da9c571d799a
Oelkers, Eric H.
3cf51d71-be44-4bed-803e-3b240bdb147b
Jones, Morgan T.
cf1c7a87-0578-4e4b-8708-a22a5b9e7df4
Pearce, Christopher R.
3d683112-72dc-444f-ae06-da9c571d799a
Oelkers, Eric H.
3cf51d71-be44-4bed-803e-3b240bdb147b

Jones, Morgan T., Pearce, Christopher R. and Oelkers, Eric H. (2012) An experimental study of the interaction of basaltic riverine particulate material and seawater. Geochimica et Cosmochimica Acta, 77, 108-120. (doi:10.1016/j.gca.2011.10.044).

Record type: Article

Abstract

The riverine transport of elements from land to ocean is an integral flux for many element cycles and an important climate regulating process over geological timescales. This flux consists of both dissolved and particulate material. The world’s rivers are estimated to transport between 16.6 and 30 Gt yr?1 of particulate material, considerably higher than the dissolved flux of ?1 Gt yr?1. Therefore, the dissolution of particulate material upon arrival in estuaries and coastal waters may be a significant flux for many elements. Here we assess the role of riverine particulate material dissolution in seawater with closed-system experiments using riverine bedload material and estuarine sediment from western Iceland mixed with open ocean seawater. Both particulate materials significantly changed the elemental concentrations of the surrounding water with substantial increases in Si concentrations indicative of silicate dissolution. Seawater in contact with bedload material shows considerable enrichment of Ca, Mg, Mn, and Ni, while Li and K concentrations decrease. Moreover, the 87Sr/86Sr of seawater decreases with time with little change in Sr concentrations, indicative of a significant two-way flux between the solid and fluid phases. Mass balance calculations indicate that 3% of the Sr contained in the original riverine bedload was released during 9 months of reaction. In contrast, the estuarine material has a negligible effect on seawater 87Sr/86Sr and transition metal concentrations, suggesting that these reactions occur when particulate material first arrives into coastal waters. Solubility calculations performed using the PHREEQC computer code confirm that primary minerals are undersaturated, while secondary minerals such as kaolinite are oversaturated in the reacted fluids. These results demonstrate that riverine transported basaltic particulate material can significantly alter the composition of seawater, although the total concentrations of many major elements in seawater are regulated by the formation of secondary phases. This behavior has important implications for nutrient supply to coastal waters and the isotopic mass balance of several elements in the oceans

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Published date: 15 January 2012
Organisations: Geochemistry

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Local EPrints ID: 342521
URI: http://eprints.soton.ac.uk/id/eprint/342521
ISSN: 0016-7037
PURE UUID: f3811a02-c767-4751-a768-924aeae309b3

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Date deposited: 07 Sep 2012 13:29
Last modified: 14 Mar 2024 11:52

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Author: Morgan T. Jones
Author: Christopher R. Pearce
Author: Eric H. Oelkers

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