Ruthenium PCP-bis(phosphinite) pincer complexes
Ruthenium PCP-bis(phosphinite) pincer complexes
The reactions of [RuHCl(CO)(PPh3)(3)] with resorcinol bis(phosphinite) pincer ligands lead to complexes of the general formula [RuCl(PCP)(CO)(PPh3)]; the crystal structure of one example has been determined. The structures of the bulky resorcinol 2-methyl4,6-di-tert-butyl resorcinol and its mono-diisopropylphosphinite derivative were also determined. Reactions of [RuCl2(PPh3)(3)] with resorcinot bis(phosphinite) ligands yield complexes of the type [RuCl(PCP)(PPh3)], while the reaction of C6H-2-Me-4,6-'Bu-2-1,3-(OPPh2) with [RuHCl(CO)(PPh3)(3)] provides a PCP-pincer complex in which the ligand has undergone 2-methyl C-H activation.
1870-1878
Bedford, R.B.
857d1836-000d-4016-b957-e54bced1eea3
Betham, M.
50e3bc6f-810a-490d-bf5a-6a51231bca20
Blake, M.E.
a098c120-b7c2-4a19-96ff-a5d865e09151
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Draper, S.M.
b0a27540-8150-4a7a-93e0-3e7c53bde58c
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Scully, P.N.
d706d1cf-b8e2-4a68-931a-8278e6e965f2
2006
Bedford, R.B.
857d1836-000d-4016-b957-e54bced1eea3
Betham, M.
50e3bc6f-810a-490d-bf5a-6a51231bca20
Blake, M.E.
a098c120-b7c2-4a19-96ff-a5d865e09151
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Draper, S.M.
b0a27540-8150-4a7a-93e0-3e7c53bde58c
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Scully, P.N.
d706d1cf-b8e2-4a68-931a-8278e6e965f2
Bedford, R.B., Betham, M., Blake, M.E., Coles, S.J., Draper, S.M., Hursthouse, M.B. and Scully, P.N.
(2006)
Ruthenium PCP-bis(phosphinite) pincer complexes.
Inorganica Chimica Acta, 359 (6), .
(doi:10.1016/j.ica.2005.07.050).
Abstract
The reactions of [RuHCl(CO)(PPh3)(3)] with resorcinol bis(phosphinite) pincer ligands lead to complexes of the general formula [RuCl(PCP)(CO)(PPh3)]; the crystal structure of one example has been determined. The structures of the bulky resorcinol 2-methyl4,6-di-tert-butyl resorcinol and its mono-diisopropylphosphinite derivative were also determined. Reactions of [RuCl2(PPh3)(3)] with resorcinot bis(phosphinite) ligands yield complexes of the type [RuCl(PCP)(PPh3)], while the reaction of C6H-2-Me-4,6-'Bu-2-1,3-(OPPh2) with [RuHCl(CO)(PPh3)(3)] provides a PCP-pincer complex in which the ligand has undergone 2-methyl C-H activation.
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Published date: 2006
Identifiers
Local EPrints ID: 44379
URI: http://eprints.soton.ac.uk/id/eprint/44379
ISSN: 0020-1693
PURE UUID: ec12f918-2823-443b-a60e-7aaa307d7f87
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Date deposited: 05 Mar 2007
Last modified: 16 Mar 2024 03:05
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Contributors
Author:
R.B. Bedford
Author:
M. Betham
Author:
M.E. Blake
Author:
S.M. Draper
Author:
P.N. Scully
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