The University of Southampton
University of Southampton Institutional Repository

1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me)

1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me)
1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me)
The structures of the compounds 1,2-bis(diphenylphosphino)-benzene, C30H24P2, [2-(diphenylphosphino)phenyl] methyl-diphenylphosphonium iodide, C31H27P2+center dot I-, and [2-(dimethylphosphino) phenyl]trimethylphosphonium iodide, C11H19P2+center dot I-, show that quaternization only occurs at one P centre and results in significantly shorter P-C bonds and larger C-P-C angles, consistent with the formal oxidation from P-III to P-V.
0108-2701
O438-O440
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7

Levason, W., Reid, G. and Webster, M. (2006) 1,2-bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C6H4(PR2)(PR2Me]I (R = Ph or Me). Acta Crystallographica Section C: Crystal Structure Communications, 62 (7), O438-O440. (doi:10.1107/S0108270106015915).

Record type: Article

Abstract

The structures of the compounds 1,2-bis(diphenylphosphino)-benzene, C30H24P2, [2-(diphenylphosphino)phenyl] methyl-diphenylphosphonium iodide, C31H27P2+center dot I-, and [2-(dimethylphosphino) phenyl]trimethylphosphonium iodide, C11H19P2+center dot I-, show that quaternization only occurs at one P centre and results in significantly shorter P-C bonds and larger C-P-C angles, consistent with the formal oxidation from P-III to P-V.

This record has no associated files available for download.

More information

Published date: 2006

Identifiers

Local EPrints ID: 44485
URI: http://eprints.soton.ac.uk/id/eprint/44485
ISSN: 0108-2701
PURE UUID: bc626957-f143-4551-97fd-8ec73ec13708
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for G. Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 05 Mar 2007
Last modified: 16 Mar 2024 02:43

Export record

Altmetrics

Contributors

Author: W. Levason ORCID iD
Author: G. Reid ORCID iD
Author: M. Webster

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×