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Complexation of alkali chloride contact ion-pairs using a 2,5-diamidopyrrole crown macrobicycle

Complexation of alkali chloride contact ion-pairs using a 2,5-diamidopyrrole crown macrobicycle
Complexation of alkali chloride contact ion-pairs using a 2,5-diamidopyrrole crown macrobicycle
A 2,5-diamidopyrrole-capped macrobicycle was synthesized and its chloride salt binding ability evaluated in polar and apolar organic solvents. X-ray crystal structures of the receptor and its sodium chloride complex were obtained and in the latter structure the salt is bound as a contact ion-pair.
Ion-pair receptor, pyrrole, crown ether, supramolecular chemistry
289-292
Mahoney, Joseph M.
1be08064-7616-4a45-9b7a-a0420c18d7be
Marshall, R. Andrew
e9ae2855-8497-408d-bd95-de5c2938f93d
Beatty, Alicia M.
64f4b5d5-a3ff-409d-8a41-999126200642
Smith, Bradley D.
fd0bfcd3-c3e7-46ac-a225-60abc125d4e8
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Mahoney, Joseph M.
1be08064-7616-4a45-9b7a-a0420c18d7be
Marshall, R. Andrew
e9ae2855-8497-408d-bd95-de5c2938f93d
Beatty, Alicia M.
64f4b5d5-a3ff-409d-8a41-999126200642
Smith, Bradley D.
fd0bfcd3-c3e7-46ac-a225-60abc125d4e8
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943

Mahoney, Joseph M., Marshall, R. Andrew, Beatty, Alicia M., Smith, Bradley D., Camiolo, Salvatore and Gale, Philip A. (2001) Complexation of alkali chloride contact ion-pairs using a 2,5-diamidopyrrole crown macrobicycle. Journal of Supramolecular Chemistry, 1, 289-292. (doi:10.1016/S1472-7862(02)00068-0).

Record type: Article

Abstract

A 2,5-diamidopyrrole-capped macrobicycle was synthesized and its chloride salt binding ability evaluated in polar and apolar organic solvents. X-ray crystal structures of the receptor and its sodium chloride complex were obtained and in the latter structure the salt is bound as a contact ion-pair.

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More information

Published date: 2001
Additional Information: Invited issue in honour of the 60th Birthday of Professor Jerry Atwood. Although the paper was submitted in 2002, it was published in 2003 in an issue dated 2001.
Keywords: Ion-pair receptor, pyrrole, crown ether, supramolecular chemistry

Identifiers

Local EPrints ID: 13521
URI: http://eprints.soton.ac.uk/id/eprint/13521
PURE UUID: 9afa8438-1915-4ae9-83f5-810c93b957dd
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 14 Dec 2004
Last modified: 19 Nov 2019 01:52

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Contributors

Author: Joseph M. Mahoney
Author: R. Andrew Marshall
Author: Alicia M. Beatty
Author: Bradley D. Smith
Author: Salvatore Camiolo
Author: Philip A. Gale ORCID iD

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