Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties.
Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties.
Four amido-pyrrole cleft anion receptors bearing one or two ferrocene reporter groups have been synthesised and crystallographically characterised. The receptors contain either a non-conjugated (1 and 3) or conjugated (2 and 4) link between the anion binding amido-pyrrole unit and the ferrocene reporter groups. The anion binding affinities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.
anion binding, pyrrole, ferrocene, self-assembly, electrochemical sensor receptor, recognition, calixpyrrole, calixpyrroles, complexation, derivatives, sapphyrin, agents, dimer
699-709
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980
2003
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980
Coles, Simon J., Denuault, Guy, Gale, Philip A., Horton, Peter N., Hursthouse, Michael B., Light, Mark E. and Warriner, Colin N.
(2003)
Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties.
Polyhedron, 22 (5), .
(doi:10.1016/S0277-5387(02)01401-8).
Abstract
Four amido-pyrrole cleft anion receptors bearing one or two ferrocene reporter groups have been synthesised and crystallographically characterised. The receptors contain either a non-conjugated (1 and 3) or conjugated (2 and 4) link between the anion binding amido-pyrrole unit and the ferrocene reporter groups. The anion binding affinities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.
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Submitted date: 17 July 2002
Published date: 2003
Additional Information:
This is an invited article in a special issue of Polyhedron: Symposia-In-Print number 25. Supramolecular Chemistry
Keywords:
anion binding, pyrrole, ferrocene, self-assembly, electrochemical sensor receptor, recognition, calixpyrrole, calixpyrroles, complexation, derivatives, sapphyrin, agents, dimer
Identifiers
Local EPrints ID: 13522
URI: http://eprints.soton.ac.uk/id/eprint/13522
ISSN: 0277-5387
PURE UUID: f0ba0dd2-fb74-480e-a8d8-e4feaa6862da
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Date deposited: 14 Dec 2004
Last modified: 16 Mar 2024 03:15
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Author:
Philip A. Gale
Author:
Peter N. Horton
Author:
Colin N. Warriner
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