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Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties.

Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties.
Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties.
Four amido-pyrrole cleft anion receptors bearing one or two ferrocene reporter groups have been synthesised and crystallographically characterised. The receptors contain either a non-conjugated (1 and 3) or conjugated (2 and 4) link between the anion binding amido-pyrrole unit and the ferrocene reporter groups. The anion binding affinities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.
anion binding, pyrrole, ferrocene, self-assembly, electrochemical sensor receptor, recognition, calixpyrrole, calixpyrroles, complexation, derivatives, sapphyrin, agents, dimer
0277-5387
699-709
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980

Coles, Simon J., Denuault, Guy, Gale, Philip A., Horton, Peter N., Hursthouse, Michael B., Light, Mark E. and Warriner, Colin N. (2003) Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties. Polyhedron, 22 (5), 699-709. (doi:10.1016/S0277-5387(02)01401-8).

Record type: Article

Abstract

Four amido-pyrrole cleft anion receptors bearing one or two ferrocene reporter groups have been synthesised and crystallographically characterised. The receptors contain either a non-conjugated (1 and 3) or conjugated (2 and 4) link between the anion binding amido-pyrrole unit and the ferrocene reporter groups. The anion binding affinities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.

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More information

Submitted date: 17 July 2002
Published date: 2003
Additional Information: This is an invited article in a special issue of Polyhedron: Symposia-In-Print number 25. Supramolecular Chemistry
Keywords: anion binding, pyrrole, ferrocene, self-assembly, electrochemical sensor receptor, recognition, calixpyrrole, calixpyrroles, complexation, derivatives, sapphyrin, agents, dimer

Identifiers

Local EPrints ID: 13522
URI: https://eprints.soton.ac.uk/id/eprint/13522
ISSN: 0277-5387
PURE UUID: f0ba0dd2-fb74-480e-a8d8-e4feaa6862da
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Guy Denuault: ORCID iD orcid.org/0000-0002-8630-9492
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 14 Dec 2004
Last modified: 06 Jun 2018 13:10

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Contributors

Author: Simon J. Coles ORCID iD
Author: Guy Denuault ORCID iD
Author: Philip A. Gale ORCID iD
Author: Peter N. Horton ORCID iD
Author: Mark E. Light ORCID iD
Author: Colin N. Warriner

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