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Solution and solid-state studies of 3,4-dichloro-2,5-diamidopyrroles: formation of an unusual anionic narcissistic dimer

Solution and solid-state studies of 3,4-dichloro-2,5-diamidopyrroles: formation of an unusual anionic narcissistic dimer
Solution and solid-state studies of 3,4-dichloro-2,5-diamidopyrroles: formation of an unusual anionic narcissistic dimer
3,4-Dichoro-1H-pyrrole-2,5-dicarboxylic acid bis-phenylamide 3 and 3,4-dichoro-1H-pyrrole-2,5-dicarboxylic acid bis-butylamide 4 have been prepared and shown to deprotonate in the presence of basic anions: the X-ray crystal structure of the tetrabutylammonium salt of 3 revealing the formation of a dimer in the solid state.
anion templated assembly, pyrrole, crystallography
1359-7345
758-759
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Shi, Andy J.
f822d1a2-165e-40f5-9428-718bab44d35d
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Shi, Andy J.
f822d1a2-165e-40f5-9428-718bab44d35d

Camiolo, Salvatore, Gale, Philip A., Hursthouse, Michael B., Light, Mark E. and Shi, Andy J. (2002) Solution and solid-state studies of 3,4-dichloro-2,5-diamidopyrroles: formation of an unusual anionic narcissistic dimer. Chemical Communications, (7), 758-759. (doi:10.1039/b200980c).

Record type: Article

Abstract

3,4-Dichoro-1H-pyrrole-2,5-dicarboxylic acid bis-phenylamide 3 and 3,4-dichoro-1H-pyrrole-2,5-dicarboxylic acid bis-butylamide 4 have been prepared and shown to deprotonate in the presence of basic anions: the X-ray crystal structure of the tetrabutylammonium salt of 3 revealing the formation of a dimer in the solid state.

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Published date: 2002
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Keywords: anion templated assembly, pyrrole, crystallography
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Identifiers

Local EPrints ID: 13580
URI: http://eprints.soton.ac.uk/id/eprint/13580
DOI: doi:10.1039/b200980c
ISSN: 1359-7345
PURE UUID: f73a46d4-7d17-454a-aa00-a273af37a933
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 14 Dec 2004
Last modified: 16 Mar 2024 03:15

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Contributors

Author: Salvatore Camiolo
Author: Philip A. Gale ORCID iD
Author: Michael B. Hursthouse
Author: Mark E. Light ORCID iD
Author: Andy J. Shi

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