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2-Amidopyrroles and 2,5-diamidopyrroles as simple anion binding agents

2-Amidopyrroles and 2,5-diamidopyrroles as simple anion binding agents
2-Amidopyrroles and 2,5-diamidopyrroles as simple anion binding agents
Four new 2-amidopyrroles and 2,5-diamidopyrroles have been synthesized and their anion complexation properties investigated. The crystal structures of these receptors have been elucidated and reveal hydrogen bonding in the solid state leading to dimer and network formation. Selectivity for oxo-anions has been demonstrated by 1H NMR titration techniques.
anion binding, supramolecular chemistry, pyrrole
0022-3263
7849-7853
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Tizzard, Graham J.
8474c0fa-40df-43a6-a662-7f3c4722dbf2
Chapman, Christopher P.
a4f4805b-b67d-4c4c-856b-78e01a2c89a0
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Tizzard, Graham J.
8474c0fa-40df-43a6-a662-7f3c4722dbf2
Chapman, Christopher P.
a4f4805b-b67d-4c4c-856b-78e01a2c89a0
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Gale, Philip A., Camiolo, Salvatore, Tizzard, Graham J., Chapman, Christopher P., Light, Mark E., Coles, Simon J. and Hursthouse, Michael B. (2001) 2-Amidopyrroles and 2,5-diamidopyrroles as simple anion binding agents. Journal of Organic Chemistry, 66 (23), 7849-7853. (doi:10.1021/jo016020g).

Record type: Article

Abstract

Four new 2-amidopyrroles and 2,5-diamidopyrroles have been synthesized and their anion complexation properties investigated. The crystal structures of these receptors have been elucidated and reveal hydrogen bonding in the solid state leading to dimer and network formation. Selectivity for oxo-anions has been demonstrated by 1H NMR titration techniques.

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More information

Published date: 2001
Keywords: anion binding, supramolecular chemistry, pyrrole

Identifiers

Local EPrints ID: 13582
URI: http://eprints.soton.ac.uk/id/eprint/13582
ISSN: 0022-3263
PURE UUID: b783ee67-55c1-4eeb-b294-c58e39b93b9f
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Graham J. Tizzard: ORCID iD orcid.org/0000-0002-1577-5779
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 14 Dec 2004
Last modified: 10 Dec 2019 01:51

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