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Metal-induced pre-organisation for anion recognition in a neutral platinum-containing receptor

Metal-induced pre-organisation for anion recognition in a neutral platinum-containing receptor
Metal-induced pre-organisation for anion recognition in a neutral platinum-containing receptor
The presence of Pt(II) allows pre-organisation of 4,4-dicarboxamidoindole-2,2-bipyridine, enhancing anion affinity with the resulting complex displaying selectivity for dihydrogen phosphate in DMSO-d6–0.5% water. Moreover the Pt(II) complex behaves as a colorimetic sensor for fluoride
1359-7345
6279-6281
Caltagirone, Claudia
9148afed-6af0-4fcd-b30e-daa3d7765dc0
Mulas, Andrea
66bb52be-4700-4446-89d5-de41cc591211
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Caltagirone, Claudia
9148afed-6af0-4fcd-b30e-daa3d7765dc0
Mulas, Andrea
66bb52be-4700-4446-89d5-de41cc591211
Isaia, Francesco
11f997fe-81a3-4298-bbdc-15e5f2bf18cc
Lippolis, Vito
d9833a14-4aab-4827-a2ba-be818871dcf5
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161

Caltagirone, Claudia, Mulas, Andrea, Isaia, Francesco, Lippolis, Vito, Gale, Philip A. and Light, Mark E. (2009) Metal-induced pre-organisation for anion recognition in a neutral platinum-containing receptor. Chemical Communications, (41), 6279-6281. (doi:10.1039/b912942a).

Record type: Article

Abstract

The presence of Pt(II) allows pre-organisation of 4,4-dicarboxamidoindole-2,2-bipyridine, enhancing anion affinity with the resulting complex displaying selectivity for dihydrogen phosphate in DMSO-d6–0.5% water. Moreover the Pt(II) complex behaves as a colorimetic sensor for fluoride

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Published date: November 2009
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Identifiers

Local EPrints ID: 144907
URI: http://eprints.soton.ac.uk/id/eprint/144907
DOI: doi:10.1039/b912942a
ISSN: 1359-7345
PURE UUID: 9a48f3c5-3dd5-4f4e-b7cf-fe58af3496e5
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 15 Apr 2010 12:47
Last modified: 14 Mar 2024 02:44

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Contributors

Author: Claudia Caltagirone
Author: Andrea Mulas
Author: Francesco Isaia
Author: Vito Lippolis
Author: Philip A. Gale ORCID iD
Author: Mark E. Light ORCID iD

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