Synthesis and structure of [{C7F15CO2}2AgAu(PPh3)]2 and its use in electrodeposition of gold–silver alloys
Synthesis and structure of [{C7F15CO2}2AgAu(PPh3)]2 and its use in electrodeposition of gold–silver alloys
[{C7F15CO2}2AgAu(PPh3)]2 is obtained in good yield from the reaction of [C7F15CO2Ag] with [ClAuPPh3] in THF solution. The crystal structure shows a zig-zag Au–Ag–Ag–Au core with fluorocarboxylate ligands bridging the Au–Ag and Ag–Ag bonds and triphenylphosphine groups bound to Au. Electrodeposition from acetonitrile yields Au–Ag alloys. The deposited alloys are Ag rich and the composition varies with deposition potential.
gold complexes, silver complexes, x-ray crystal structures, electrodeposition
1048-1051
Bartlett, Philip N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Cheng, Fei
a0339c70-2a78-4078-8845-62759ac926d3
Cook, David A.
0fca0ffb-eef4-422f-b513-ce9a1f7de7cc
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Zhang, Wenjian
1f80ac5e-d4c2-4720-b19e-be700cd411e7
22 March 2010
Bartlett, Philip N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Cheng, Fei
a0339c70-2a78-4078-8845-62759ac926d3
Cook, David A.
0fca0ffb-eef4-422f-b513-ce9a1f7de7cc
Hector, Andrew L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Zhang, Wenjian
1f80ac5e-d4c2-4720-b19e-be700cd411e7
Bartlett, Philip N., Cheng, Fei, Cook, David A., Hector, Andrew L., Levason, William, Reid, Gillian and Zhang, Wenjian
(2010)
Synthesis and structure of [{C7F15CO2}2AgAu(PPh3)]2 and its use in electrodeposition of gold–silver alloys.
Inorganica Chimica Acta, 363 (5), .
(doi:10.1016/j.ica.2009.12.030).
Abstract
[{C7F15CO2}2AgAu(PPh3)]2 is obtained in good yield from the reaction of [C7F15CO2Ag] with [ClAuPPh3] in THF solution. The crystal structure shows a zig-zag Au–Ag–Ag–Au core with fluorocarboxylate ligands bridging the Au–Ag and Ag–Ag bonds and triphenylphosphine groups bound to Au. Electrodeposition from acetonitrile yields Au–Ag alloys. The deposited alloys are Ag rich and the composition varies with deposition potential.
This record has no associated files available for download.
More information
Published date: 22 March 2010
Keywords:
gold complexes, silver complexes, x-ray crystal structures, electrodeposition
Identifiers
Local EPrints ID: 145939
URI: http://eprints.soton.ac.uk/id/eprint/145939
ISSN: 0020-1693
PURE UUID: 79358ff5-b2ce-4e59-8027-4f5cfda32b9a
Catalogue record
Date deposited: 20 Apr 2010 09:11
Last modified: 14 Mar 2024 02:39
Export record
Altmetrics
Contributors
Author:
Fei Cheng
Author:
David A. Cook
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
