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Bis(?5-cyclopentadienyl)bis(2,4,6-trimethylphenyltellurolato)zirconium(IV)

Bis(?5-cyclopentadienyl)bis(2,4,6-trimethylphenyltellurolato)zirconium(IV)
Bis(?5-cyclopentadienyl)bis(2,4,6-trimethylphenyltellurolato)zirconium(IV)
The structure of the title compound, [Zr(C5H5)2(C9H11Te)2], consists of a zirconium(IV) centre bonded to two 5-coordinated cyclopentadienyl groups and two mesityltellurolate ligands; the discrete molecule has crystallographic twofold rotation symmetry. The structural parameters compared with those in [(5-Me5Cp)2Zr(TePh)2] [Howard, Trnka & Parkin (1995). Inorg. Chem. 34, 5900-5909] show that the greater steric demands of the bulky mesityl substituents are accommodated by widening Te-Zr-Te (8°) and by more acute Zr-Te-C (5°) angles, although the Zr-Te distances are essentially the same. The crystal studied exhibited some inversion twinning.
complexes
m667
Hector, A.L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Reid, S.D.
e2c3e0f2-5bde-4959-bcdd-5e8a54369317
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Hector, A.L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Reid, S.D.
e2c3e0f2-5bde-4959-bcdd-5e8a54369317
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7

Hector, A.L., Levason, W., Reid, G., Reid, S.D. and Webster, M. (2008) Bis(?5-cyclopentadienyl)bis(2,4,6-trimethylphenyltellurolato)zirconium(IV). Acta Crystallographica Section E: Structure Reports Online, 64 (5), m667. (doi:10.1107/S1600536808009574).

Record type: Article

Abstract

The structure of the title compound, [Zr(C5H5)2(C9H11Te)2], consists of a zirconium(IV) centre bonded to two 5-coordinated cyclopentadienyl groups and two mesityltellurolate ligands; the discrete molecule has crystallographic twofold rotation symmetry. The structural parameters compared with those in [(5-Me5Cp)2Zr(TePh)2] [Howard, Trnka & Parkin (1995). Inorg. Chem. 34, 5900-5909] show that the greater steric demands of the bulky mesityl substituents are accommodated by widening Te-Zr-Te (8°) and by more acute Zr-Te-C (5°) angles, although the Zr-Te distances are essentially the same. The crystal studied exhibited some inversion twinning.

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More information

Published date: May 2008
Keywords: complexes
Organisations: Chemistry

Identifiers

Local EPrints ID: 145959
URI: http://eprints.soton.ac.uk/id/eprint/145959
PURE UUID: cf816159-4fca-4ff9-b2fd-631d7bd4fe74
ORCID for A.L. Hector: ORCID iD orcid.org/0000-0002-9964-2163
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for G. Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 20 Apr 2010 08:55
Last modified: 20 Jul 2019 01:28

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Contributors

Author: A.L. Hector ORCID iD
Author: W. Levason ORCID iD
Author: G. Reid ORCID iD
Author: S.D. Reid
Author: M. Webster

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